An eco-friendly way to fire retardant flexible polyurethane foam: layer-by-layer assembly of fully bio-based substances

The objective of the present study is to develop fully renewable and environmentally benign techniques for improving the fire safety of flexible polyurethane foams (PUFs). A multilayered coating made from cationic chitosan (CS) and anionic alginate (AL) was deposited on PUFs through layer-by-layer assembly. This coating system exhibits a slight influence on the thermal stability of PUF, but significantly improves the char formation during combustion. Cone calorimetry reveals that 10 CS-AL bilayers (only 5.7% of the foams weight) lead to a 66% and 11% reduction in peak heat release rate and total heat release, respectively, compared with those of the uncoated control. The notable decreased fire hazards of PUF are attributed to the CS-AL coatings being beneficial to form an insulating protective layer on the surface of burning materials that inhibits the oxygen and heat permeation and slows down the flammable gases in the vapor phase, and thereby improves the flame resistance. This water-based, environmentally benign natural coating will stimulate further efforts in improving fire safety for a variety of polymer substrates.

Intelligent context-aware services based on internet of things architectures

La Internet de las Cosas (IoT), como parte de la Futura Internet, se ha convertido en la actualidad en uno de los principales temas de investigación; en parte gracias a la atención que la sociedad está poniendo en el desarrollo de determinado tipo de servicios (telemetría, generación inteligente de energía, telesanidad, etc.) y por las recientes previsiones económicas que sitúan a algunos actores, como los operadores de telecomunicaciones (que se encuentran desesperadamente buscando nuevas oportunidades), al frente empujando algunas tecnologías interrelacionadas como las comunicaciones Máquina a Máquina (M2M). En este contexto, un importante número de actividades de investigación a nivel mundial se están realizando en distintas facetas: comunicaciones de redes de sensores, procesado de información, almacenamiento de grandes cantidades de datos (big--‐data), semántica, arquitecturas de servicio, etc. Todas ellas, de forma independiente, están llegando a un nivel de madurez que permiten vislumbrar la realización de la Internet de las Cosas más que como un sueño, como una realidad tangible. Sin embargo, los servicios anteriormente mencionados no pueden esperar a desarrollarse hasta que las actividades de investigación obtengan soluciones holísticas completas. Es importante proporcionar resultados intermedios que eviten soluciones verticales realizadas para desarrollos particulares. En este trabajo, nos hemos focalizado en la creación de una plataforma de servicios que pretende facilitar, por una parte la integración de redes de sensores y actuadores heterogéneas y geográficamente distribuidas, y por otra lado el desarrollo de servicios horizontales utilizando dichas redes y la información que proporcionan. Este habilitador se utilizará para el desarrollo de servicios y para la experimentación en la Internet de las Cosas. Previo a la definición de la plataforma, se ha realizado un importante estudio focalizando no sólo trabajos y proyectos de investigación, sino también actividades de estandarización. Los resultados se pueden resumir en las siguientes aseveraciones: a) Los modelos de datos definidos por el grupo “Sensor Web Enablement” (SWE™) del “Open Geospatial Consortium (OGC®)” representan hoy en día la solución más completa para describir las redes de sensores y actuadores así como las observaciones. b) Las interfaces OGC, a pesar de las limitaciones que requieren cambios y extensiones, podrían ser utilizadas como las bases para acceder a sensores y datos. c) Las redes de nueva generación (NGN) ofrecen un buen sustrato que facilita la integración de redes de sensores y el desarrollo de servicios. En consecuencia, una nueva plataforma de Servicios, llamada Ubiquitous Sensor Networks (USN), se ha definido en esta Tesis tratando de contribuir a rellenar los huecos previamente mencionados. Los puntos más destacados de la plataforma USN son: a) Desde un punto de vista arquitectónico, sigue una aproximación de dos niveles (Habilitador y Gateway) similar a otros habilitadores que utilizan las NGN (como el OMA Presence). b) Los modelos de datos están basado en los estándares del OGC SWE. iv c) Está integrado en las NGN pero puede ser utilizado sin ellas utilizando infraestructuras IP abiertas. d) Las principales funciones son: Descubrimiento de sensores, Almacenamiento de observaciones, Publicacion--‐subscripcion--‐notificación, ejecución remota homogénea, seguridad, gestión de diccionarios de datos, facilidades de monitorización, utilidades de conversión de protocolos, interacciones síncronas y asíncronas, soporte para el “streaming” y arbitrado básico de recursos. Para demostrar las funcionalidades que la Plataforma USN propuesta pueden ofrecer a los futuros escenarios de la Internet de las Cosas, se presentan resultados experimentales de tres pruebas de concepto (telemetría, “Smart Places” y monitorización medioambiental) reales a pequeña escala y un estudio sobre semántica (sistema de información vehicular). Además, se está utilizando actualmente como Habilitador para desarrollar tanto experimentación como servicios reales en el proyecto Europeo SmartSantander (que aspira a integrar alrededor de 20.000 dispositivos IoT). v Abstract Internet of Things, as part of the Future Internet, has become one of the main research topics nowadays; in part thanks to the pressure the society is putting on the development of a particular kind of services (Smart metering, Smart Grids, eHealth, etc.), and by the recent business forecasts that situate some players, like Telecom Operators (which are desperately seeking for new opportunities), at the forefront pushing for some interrelated technologies like Machine--‐to--‐Machine (M2M) communications. Under this context, an important number of research activities are currently taking place worldwide at different levels: sensor network communications, information processing, big--‐ data storage, semantics, service level architectures, etc. All of them, isolated, are arriving to a level of maturity that envision the achievement of Internet of Things (IoT) more than a dream, a tangible goal. However, the aforementioned services cannot wait to be developed until the holistic research actions bring complete solutions. It is important to come out with intermediate results that avoid vertical solutions tailored for particular deployments. In the present work, we focus on the creation of a Service--‐level platform intended to facilitate, from one side the integration of heterogeneous and geographically disperse Sensors and Actuator Networks (SANs), and from the other the development of horizontal services using them and the information they provide. This enabler will be used for horizontal service development and for IoT experimentation. Prior to the definition of the platform, we have realized an important study targeting not just research works and projects, but also standardization topics. The results can be summarized in the following assertions: a) Open Geospatial Consortium (OGC®) Sensor Web Enablement (SWE™) data models today represent the most complete solution to describe SANs and observations. b) OGC interfaces, despite the limitations that require changes and extensions, could be used as the bases for accessing sensors and data. c) Next Generation Networks (NGN) offer a good substrate that facilitates the integration of SANs and the development of services. Consequently a new Service Layer platform, called Ubiquitous Sensor Networks (USN), has been defined in this Thesis trying to contribute to fill in the previous gaps. The main highlights of the proposed USN Platform are: a) From an architectural point of view, it follows a two--‐layer approach (Enabler and Gateway) similar to other enablers that run on top of NGN (like the OMA Presence). b) Data models and interfaces are based on the OGC SWE standards. c) It is integrated in NGN but it can be used without it over open IP infrastructures. d) Main functions are: Sensor Discovery, Observation Storage, Publish--‐Subscribe--‐Notify, homogeneous remote execution, security, data dictionaries handling, monitoring facilities, authorization support, protocol conversion utilities, synchronous and asynchronous interactions, streaming support and basic resource arbitration. vi In order to demonstrate the functionalities that the proposed USN Platform can offer to future IoT scenarios, some experimental results have been addressed in three real--‐life small--‐scale proofs--‐of concepts (Smart Metering, Smart Places and Environmental monitoring) and a study for semantics (in--‐vehicle information system). Furthermore we also present the current use of the proposed USN Platform as an Enabler to develop experimentation and real services in the SmartSantander EU project (that aims at integrating around 20.000 IoT devices).

Building functional surfaces for biosensors development

Polyelectrolyte multilayers (PEM) built by layer-by-layer technique have been extensively studied over the last years, resulting in a wide variety of current and potential applications. This technique can be used to construct thin films with different functionalities, or to functionalize surfaces with substantial different properties of those of the underlying substrates. The multilayering process is achieved by the alternate adsorption of oppositely charged polyelectrolytes. In this work we get advantage of the protein resistant property of the Poly (l-lysine)-graft-(polyethyleneglycol) to create protein patterns. Proteins can be immobilized on a surface by unspecific physical adsorption, covalent binding or through specific interactions. The first protein used in this work was laccase, a copper-containing redox enzyme that catalyse the oxidation of a broad range of polyphenols and aromatic substrates, coupled to the reduction of O2 to H2O without need of cofactors. Applications of laccases have been reported in food, pulp, paper, and textile industry, and also in biosensor development. Some uses require the immobilization of the enzyme on solid supports by adsorption, covalent attachment, entrapment, etc, on several substrates. Especially for biosensor development, highly active, stable and reproducible immobilization of laccase is required.

Modeling Commercial Knowledge to Develop Advanced Agent-based Marketplaces for E-commerce

This paper argues about the utility of advanced knowledge-based techniques to develop web-based applications that help consumers in finding products within marketplaces in e-commerce. In particular, we describe the idea of model-based approach to develop a shopping agent that dynamically configures a product according to the needs and preferences of customers. Finally, the paper summarizes the advantages provided by this approach.

Las lecturas de Sáenz de Oíza. Desde Torres Blancas al Banco de Bilbao a través de una selección de textos hecha por el propio arquitecto.

El 29 de enero de 2000 Francisco Javier Sáenz de Oíza ofrece su última conferencia en el salón de actos del edificio sede del BBVA en el Paseo de la Castellana de Madrid. Esta conferencia inaugura el ciclo “El arquitecto enseña su obra”, organizado por el Colegio Oficial de Arquitectos de Madrid (C.O.A.M.) y la Escuela Técnica Superior de Arquitectura de Madrid (E.T.S.A.M.). Las obras en concreto que Oíza 'enseña' en este evento son Torres Blancas (Madrid, 1961- 1968) y Banco de Bilbao (Madrid, 1971-1980). Antes de la conferencia, blandiendo una carpeta, Oíza dice: Traigo aquí los textos de siempre, los que siempre he usado, (...) yo no he escrito ni una línea, solo he subrayado ciertos pasajes, en la medida de lo posible me gustaría leer alguno. Pero como aquí hay como para cinco horas, pues no se qué hacer. Citarlo sí, porque de ustedes el que quiera penetrar un poco en mi conocimiento, pues que vea las citas que yo hago aquí, qué pasajes, o qué libros o qué artículos propongo. 1 La carpeta que lleva Oíza en su mano contiene veinticuatro fichas mecanografiadas por él mismo. Las fichas son pasajes de textos; en su mayoría de textos literarios o poéticos, e incluyen una referencia bibliográfica que menciona: título de libro, edición y número de página. Además, en cada ficha están resaltados los pasajes que Oíza pretende leer. 2 Antes del comienzo de la conferencia Oíza dice: Tengo aquí citas de lecturas que le recomendaría a quien quiera enterarse de cómo es este edificio. 3 Durante la conferencia Oíza no parece hablar sobre las obras que debe enseñar; en cambio se dedica, casi exclusivamente, a leer en público. Esta tesis nace de lo sugerido por el propio Oíza. El objetivo general, siguiendo sus propias palabras, es 'penetrar un poco' en su conocimiento a partir de citas y recomendaciones de lecturas realizadas por él mismo al tratar sobre arquitectura. La hipótesis central plantea que por medio de sus lecturas Oíza sí habla de arquitectura, y sostiene también que a partir de sus textos es posible 'enterarse', al menos en parte, de cómo es un edificio, en particular Torres Blancas y Banco de Bilbao. Más aún, se plantea la hipótesis de que Oíza, maestro ágrafo y de carácter socrático, ha construido, no obstante, un 'discurso teórico' arquitectónico suficientemente sistemático. De modo que aún cuando Oíza no ha dejado una 'teoría' escrita es posible reconstruirla, en cierta medida, a partir de su elocución y a partir de la comprensión de sus 'lecturas'. Las fuentes primarias de esta tesis son: a) Las lecturas que Oíza recomienda en su conferencia de enero de 2000. b) Torres Blancas y Banco de Bilbao. c) Las lecturas en público realizadas por Oíza en conferencias, cursos, debates, mesas redondas, programas de TV, etc. El tema que se investiga es la relación entre los textos recomendados por Oíza y su arquitectura, y la pregunta guía de la investigación es cómo y en qué medida los textos pueden contribuir a la comprensión del pensamiento, del discurso y de la obra de Oíza. Torres Blancas y Banco de Bilbao son, en todo momento, las dos principales obras utilizadas para la observación y el contraste de los resultados de la investigación teórica en el desarrollo de la tesis. El soporte teórico y metodológico de la tesis está dado por la hermenéutica en tanto disciplina encargada de la interpretación y correcta comprensión de textos y obras, en particular por la filosofía hermenéutica de Hans-Georg Gadamer expuesta en Verdad y método. La relevancia, el aspecto original y la posible aportación al conocimiento de esta tesis consiste en una aproximación a Oíza y a su arquitectura, desde un punto de vista hasta ahora no investigado de forma sistemática, esto es, a partir de las lecturas de Oíza. ABSTRACT On 29th January 2000 Francisco Javier Sáenz de Oíza gave his last lecture in the Auditorium at BBVA headquarters located in Paseo de la Castellana avenue in Madrid. That lecture opened the series The Architect Shows his Work (El arquitecto enseña su obra) organised by the COAM Official College of Architects and the ETSAM Architecture School of Madrid. The specific works that Oíza 'shows' in his lecture were Torres Blancas (Madrid, 1961- 1968) and Banco de Bilbao (Madrid, 1971-1980). Before the lecture, waving a folder in his hand, Oíza says: I've got here the texts I've always used, (…) I haven't written a line, I've only underlined certain passages, I would like to read some of them to the extent possible. But I have here about five hours of reading, so I don't know what to do. I can cite them, yes, and anyone of you who want to delve a little into my knowledge can look at the citations I make here, the passages, books or articles I recommend. 1 The folder in Oíza's hand contains 24 files typed by the architect himself. The files consist of text passages -most of which are literary or poetry texts- and include the bibliographic citation with book the title, edition and page number. In addition, the passages Oíza intends to read are highlighted. Before starting his lecture Oíza says: I've got here citations of readings I'd recommend to those who want to realise how this building is. 2 During the lecture Oíza doesn't seem to be talking about the works he has to show, on the contrary, he focuses almost exclusively on reading texts to the audience. This thesis is the result of a suggestion made by Oíza himself. The broad aim is to 'delve a little into' his knowledge using citations and reading recommendations made by Oíza when dealing with the architecture subject. The main hypothesis proposes that Oíza talks about architecture through his readings and that starting from 'his' texts it is possible to 'realise', at least in part, how a building is, Torres Blancas and Banco de Bilbao in particular. Moreover, it is proposed the hypothesis that Oíza, as a Socratic teacher reluctant to write down his ideas, has nevertheless built a systematic 'theoretical discourse' on architecture. As a result, even when he has not written a 'theory', it is possible to reconstruct it to a certain degree, starting from his speech and from the understanding of his readings. The primary sources for this thesis are: a) The readings that Oíza recommends in his lecture of January 2000. b) The Torres Blancas and Banco de Bilbao. c) The readings done by Oíza in presentations, lectures, debates, panel discussions, television programmes, etc. The subject under research is the relationship between the texts that Oíza recommends and his architecture. The guiding question for the research is how and to what extent the texts can contribute to the understanding of Oíza's thoughts, discourse and work. Torres Blancas and Banco de Bilbao are the two main works considered along the thesis and they have been used for observation and to test the results of the theoretical research as it progresses. The thesis theoretical and methodological framework is based on the hermeneutics -as the discipline that deals with the interpretation and the correct understanding of texts and works-, in particular the hermeneutics philosophy of Hans-Georg Gadamer in Truth and Method. The relevance, the original element and the possible contribution of this thesis is given by the approach to Oíza and his architecture through Oíza's readings, a perspective that hasn't been yet systematically researched.

Engineering privacy requirements valuable lessons from another realm

The Privacy by Design approach to systems engineering introduces privacy requirements in the early stages of development, instead of patching up a built system afterwards. However, 'vague', 'disconnected from technology', or 'aspirational' are some terms employed nowadays to refer to the privacy principles which must lead the development process. Although privacy has become a first-class citizen in the realm of non-functional requirements and some methodological frameworks help developers by providing design guidance, software engineers often miss a solid reference detailing which specific, technical requirements they must abide by, and a systematic methodology to follow. In this position paper, we look into a domain that has already successfully tackled these problems -web accessibility-, and propose translating their findings into the realm of privacy requirements engineering, analyzing as well the gaps not yet covered by current privacy initiatives.

Discourses and values underpin public debate on fracking in Spain: a case study at the crossroad

In the EU context extraction of shale and oil gas by hydraulic fracturing (fracking) differs from country to country in terms of legislation and implementation. While fossil fuel extraction using this technology is currently taking place in the UK, Germany and France have adopted respective moratoria. In between is the Spanish case, where hydrocarbon extraction projects through fracking have to undergo mandatory and routine environmental assessment in accordance with the last changes to environmental regulations. Nowadays Spain is at the crossroad with respect to the future of this technology. We presume a social conflictt in our country since the position and strategy of the involved and confronted social actors -national, regional and local authorities, energy companies, scientists, NGO and other social organization- are going to play key and likely divergent roles in its industrial implementation and public acceptance. In order to improve knowledge on how to address these controverted situations from the own engineering context, the affiliated units from the Higher Technical School of Mines and Energy Engineering at UPM have been working on a transversal program to teach values and ethics. Over the past seven years, this pioneering experience has shown the usefulness of applying a consequentialist ethics, based on a case-by-case approach and costs-benefits analysis both for action and inaction. As a result of this initiative a theoretical concept has arisen and crystallized in this field: it is named Inter-ethics. This theoretical perspective can be very helpful in complex situations, with multi-stakeholders and plurality of interests, when ethical management requires the interaction between the respective ethics of each group; professional ethics of a single group is not enough. Under this inter-ethics theoretical framework and applying content analysis techniques, this paper explores the articulation of the discourse in favour and against fracking technology and its underlying values as manifested in the Spanish traditional mass media and emerging social media such as Youtube. Results show that Spanish public discourse on fracking technology includes the costs-benefits analysis to communicate how natural resources from local communities may be affected by these facilities due to environmental, health and economic consequences. Furthermore, this technology is represented as a solution to the "demand of energy" according to the optimistic discourse while, from a pessimistic view, fracking is often framed as a source "environmental problems" and even natural disasters as possible earthquakes. In this latter case, this negative representation could have been influenced by the closure of a macro project to store injected natural gas in the Mediterranean Sea using the old facilities of an oil exploitation in Amposta (Proyecto Cástor). The closure of this project was due to the occurrence of earthquakes whose intensity was higher than the originally expected by the experts in the assessment stage of the project.