38 resultados para Layered stannosilicates
Resumo:
In order to perform finite element (FE) analyses of patient-specific abdominal aortic aneurysms, geometries derived from medical images must be meshed with suitable elements. We propose a semi-automatic method for generating conforming hexahedral meshes directly from contours segmented from medical images. Magnetic resonance images are generated using a protocol developed to give the abdominal aorta high contrast against the surrounding soft tissue. These data allow us to distinguish between the different structures of interest. We build novel quadrilateral meshes for each surface of the sectioned geometry and generate conforming hexahedral meshes by combining the quadrilateral meshes. The three-layered morphology of both the arterial wall and thrombus is incorporated using parameters determined from experiments. We demonstrate the quality of our patient-specific meshes using the element Scaled Jacobian. The method efficiently generates high-quality elements suitable for FE analysis, even in the bifurcation region of the aorta into the iliac arteries. For example, hexahedral meshes of up to 125,000 elements are generated in less than 130 s, with 94.8 % of elements well suited for FE analysis. We provide novel input for simulations by independently meshing both the arterial wall and intraluminal thrombus of the aneurysm, and their respective layered morphologies.
Resumo:
Teniendo en cuenta que no hay nada que se escape de la moda 1, y extendiendonos más allá de esta manida discusión sobre intersecciones formales, esta investigación propone la pasarela como un lugar real de mediación entre moda y arquitectura. Asumiendo esta condición, la pasarela encarna nuevos modos de producción apropiándose de su espacio y estructura, y convierténdose en una máquina capaz de generar múltiples y más bien infinitos significados. La moda es sin duda un proyecto creativo, que ha venido utilizando la pasarela como un marco para la reordenación de su narrativa visual, renovándose asi mismo como fenómeno social. Este proyecto de investigación plantea, que contrariamente las tipologías actuales de las pasarelas no nos facilitan la comprensión de una colección – que suele ser el objetivo principal. Presentan en cambio un entorno en el que se acoplan diferentes formatos visuales, -con varias capas-, conviéndolo en una compleja construcción y provocando nunerosas fricciones con el espacio-tiempo-acción durante el proceso de creación de otros territorios. Partiendo de la idea de la pasarela como un sistema, en el que sus numerosas variables pueden producir diversas combinaciones, esta investigación plantea la hipótesis por la cual un nuevo sistema de pasarela se estaría formando enteramente con capas de información. Este escenario nos conduciría a la inmersión final de la moda en los tejidos de la virtualidad. Si bien el debate sobre la relevancia de los desfiles de moda se ha vuelto más evidente hoy en día, esta investigación especula con la posibilidad del pensamiento arquitectónico y como este puede introducir metodologías de análisis en el marco de estos desfiles de moda, proponiendo una lectura de la pasarela como un sistema de procedimientos específicos inherente a los proyectos/procesos de la arquitectura. Este enfoque enlaza ambas prácticas en un territorio común donde el espacio, el diseño, el comportamiento, el movimiento, y los cuerpos son ordenados/organizados en la creación de estas nuevas posibilidades visuales, y donde las interacciones activan la generación de la novedad y los mensajes. PALABRAS CLAVES moda, sistema, virtual, información, arquitectura Considering that there is nothing left untouched by fashion2, and going beyond the already exhausted discussion about formal intersections, this research introduces the catwalk as the real arena of mediation between fashion and architecture. By assuming this condition, the catwalk embodies new modes of production that appropriates its space and turns it into a machine for generating multiple if not infinite meanings. Fashion, as a creative project, has utilized the catwalk as a frame for rearranging its visual narrative and renewing itself as social phenomena. This research disputes, however, that the current typologies of catwalks do not facilitate the understanding of the collection – as its primary goal - but, instead, present an environment composed of multi-layered visual formats, becoming a complex construct that collides space-time-action in the creation of other territories. Departing from the analysis of the catwalk as a system and how its many variables can produce diverse combinations, this research presents the hypothesis that a new system is being formed entirely built out of information. Such scenario indicates fashion´s final immersion into the fabrics of virtuality. While the discussion about the relevance of fashion shows has become more evident today, this research serves as an introductory speculation on how architectural thinking can introduce methodologies of analysis within the framework of the fashion shows, by proposing a reading of the catwalk as a system through specific procedures that are inherent to architectural projects. Such approach intertwines both practices into a common territory where space, design, behaviour, movement, and bodies are organized for the creation of visual possibilities, and where interactions are triggered in the making of novelty and messages. KEYWORDS fashion, system, virtual, information, architectural
Resumo:
Limit equilibrium is a common method used to analyze the stability of a slope, and minimization of the factor of safety or identification of critical slip surfaces is a classical geotechnical problem in the context of limit equilibrium methods for slope stability analyses. A mutative scale chaos optimization algorithm is employed in this study to locate the noncircular critical slip surface with Spencer’s method being employed to compute the factor of safety. Four examples from the literature—one homogeneous slope and three layered slopes—are employed to identify the efficiency and accuracy of this approach. Results indicate that the algorithm is flexible and that although it does not generally provide the minimum FS, it provides results that are close to the minimum, an improvement over other solutions proposed in the literature and with small relative errors with respect to other minimum factor of safety (FS) values reported in the literature.
Resumo:
The paper reports on a collaborative effort between the Swiss Federal Nuclear Safety Inspectorate (ENSI) and their consultants Principia and Stangenberg. As part of the IMPACT III project, reduced scale impact tests of reinforced concrete structures were carried out. The simulation of test X3 is presented here and the numerical results are compared with those obtained in the test, carried out in August 2013. The general object is to improve the safety of nuclear facilities and, more specifically, to demonstrate the capabilities of current simulation techniques to reproduce the behaviour of a reinforced concrete structure impacted by a soft missile. The missile is a steel tube with a mass of 50 kg and travelling at 140 m/s. The target is a 250 mm thick, 2,1 m by 2,1 m reinforced concrete wall, held in a stiff supporting frame. The reinforcement includes both longitudinal and transverse rebars. Calculations were carried out before and after the test with Abaqus (Principia) and SOFiSTiK (Stangenberg). In the Abaqus simulation the concrete is modelled using solid elements and a damaged plasticity formulation, the rebars with embedded beam elements, and the missile with shell elements. In SOFiSTiK the target is modelled with non-linear, layered shell elements for the reinforcement on both sides; non-linear shear deformations of shell/plate elements are approximately included. The results generally indicate a good agreement between calculations and measurements.
Resumo:
Los análisis de fiabilidad representan una herramienta adecuada para contemplar las incertidumbres inherentes que existen en los parámetros geotécnicos. En esta Tesis Doctoral se desarrolla una metodología basada en una linealización sencilla, que emplea aproximaciones de primer o segundo orden, para evaluar eficientemente la fiabilidad del sistema en los problemas geotécnicos. En primer lugar, se emplean diferentes métodos para analizar la fiabilidad de dos aspectos propios del diseño de los túneles: la estabilidad del frente y el comportamiento del sostenimiento. Se aplican varias metodologías de fiabilidad — el Método de Fiabilidad de Primer Orden (FORM), el Método de Fiabilidad de Segundo Orden (SORM) y el Muestreo por Importancia (IS). Los resultados muestran que los tipos de distribución y las estructuras de correlación consideradas para todas las variables aleatorias tienen una influencia significativa en los resultados de fiabilidad, lo cual remarca la importancia de una adecuada caracterización de las incertidumbres geotécnicas en las aplicaciones prácticas. Los resultados también muestran que tanto el FORM como el SORM pueden emplearse para estimar la fiabilidad del sostenimiento de un túnel y que el SORM puede mejorar el FORM con un esfuerzo computacional adicional aceptable. Posteriormente, se desarrolla una metodología de linealización para evaluar la fiabilidad del sistema en los problemas geotécnicos. Esta metodología solamente necesita la información proporcionada por el FORM: el vector de índices de fiabilidad de las funciones de estado límite (LSFs) que componen el sistema y su matriz de correlación. Se analizan dos problemas geotécnicos comunes —la estabilidad de un talud en un suelo estratificado y un túnel circular excavado en roca— para demostrar la sencillez, precisión y eficiencia del procedimiento propuesto. Asimismo, se reflejan las ventajas de la metodología de linealización con respecto a las herramientas computacionales alternativas. Igualmente se muestra que, en el caso de que resulte necesario, se puede emplear el SORM —que aproxima la verdadera LSF mejor que el FORM— para calcular estimaciones más precisas de la fiabilidad del sistema. Finalmente, se presenta una nueva metodología que emplea Algoritmos Genéticos para identificar, de manera precisa, las superficies de deslizamiento representativas (RSSs) de taludes en suelos estratificados, las cuales se emplean posteriormente para estimar la fiabilidad del sistema, empleando la metodología de linealización propuesta. Se adoptan tres taludes en suelos estratificados característicos para demostrar la eficiencia, precisión y robustez del procedimiento propuesto y se discuten las ventajas del mismo con respecto a otros métodos alternativos. Los resultados muestran que la metodología propuesta da estimaciones de fiabilidad que mejoran los resultados previamente publicados, enfatizando la importancia de hallar buenas RSSs —y, especialmente, adecuadas (desde un punto de vista probabilístico) superficies de deslizamiento críticas que podrían ser no-circulares— para obtener estimaciones acertadas de la fiabilidad de taludes en suelos. Reliability analyses provide an adequate tool to consider the inherent uncertainties that exist in geotechnical parameters. This dissertation develops a simple linearization-based approach, that uses first or second order approximations, to efficiently evaluate the system reliability of geotechnical problems. First, reliability methods are employed to analyze the reliability of two tunnel design aspects: face stability and performance of support systems. Several reliability approaches —the first order reliability method (FORM), the second order reliability method (SORM), the response surface method (RSM) and importance sampling (IS)— are employed, with results showing that the assumed distribution types and correlation structures for all random variables have a significant effect on the reliability results. This emphasizes the importance of an adequate characterization of geotechnical uncertainties for practical applications. Results also show that both FORM and SORM can be used to estimate the reliability of tunnel-support systems; and that SORM can outperform FORM with an acceptable additional computational effort. A linearization approach is then developed to evaluate the system reliability of series geotechnical problems. The approach only needs information provided by FORM: the vector of reliability indices of the limit state functions (LSFs) composing the system, and their correlation matrix. Two common geotechnical problems —the stability of a slope in layered soil and a circular tunnel in rock— are employed to demonstrate the simplicity, accuracy and efficiency of the suggested procedure. Advantages of the linearization approach with respect to alternative computational tools are discussed. It is also found that, if necessary, SORM —that approximates the true LSF better than FORM— can be employed to compute better estimations of the system’s reliability. Finally, a new approach using Genetic Algorithms (GAs) is presented to identify the fully specified representative slip surfaces (RSSs) of layered soil slopes, and such RSSs are then employed to estimate the system reliability of slopes, using our proposed linearization approach. Three typical benchmark-slopes with layered soils are adopted to demonstrate the efficiency, accuracy and robustness of the suggested procedure, and advantages of the proposed method with respect to alternative methods are discussed. Results show that the proposed approach provides reliability estimates that improve previously published results, emphasizing the importance of finding good RSSs —and, especially, good (probabilistic) critical slip surfaces that might be non-circular— to obtain good estimations of the reliability of soil slope systems.
Resumo:
Intermediate-band materials can improve the photovoltaic efficiency of solar cells through the absorption of two subband-gap photons that allow extra electron-hole pair formations. Previous theoretical and experimental findings support the proposal that the layered SnS2 compound, with a band-gap of around 2 eV, is a candidate for an intermediate-band material when it is doped with a specific transition-metal. In this work we characterize vanadium doped SnS2 using density functional theory at the dilution level experimentally found and including a dispersion correction combined with the site-occupancy-disorder method. In order to analyze the electronic characteristics that depend on geometry, two SnS2 polytypes partially substituted with vanadium in symmetry-adapted non-equivalent configurations were studied. In addition the magnetic configurations of vanadium in a SnS2 2H-polytype and its comparison with a 4H-polytype were also characterized. We demonstrate that a narrow intermediate-band is formed, when these dopant atoms are located in different layers. Our theoretical predictions confirm the recent experimental findings in which a paramagnetic intermediate-band material in a SnS2 2H-polytype with 10% vanadium concentration is obtained.
Resumo:
La presente tesis doctoral se centra en la investigación del "estrato arquitectónico", manejando conceptos, lógicas y sinopsis como puntos organizativos, enlazados y superpuestos, que den paso a un marco propositivo que pueda ser simultáneamente articulado e independiente. Una situación que, ante nuevos desafíos, pretende ir más allá de una estricta definición de estrato o de su noción preconcebida descrita desde la superposición de diversos materiales. Todo ello a fin de revelar los diferentes perfiles del estrato y de la estratificación. Para ello, se abre y amplía el campo de estudio proyectual/procesual desdibujando los límites entre disciplinas –geología, filosofía, tecnología, arquitectura–. Y al mismo tiempo, se construye una cartografía del estrato arquitectónico asociada: a una taxonomía descriptora, a nuevas formulaciones, a pensamientos de personajes reconocibles y/o rescatados –como Rowe/Slutzky, Smithson, Parent/Virilio, Koolhaas, MVRDV, etc.–, y, por último, a nuevas lógicas proyectuales y operativas referidas al estrato, que fusionan conocimientos complejos. Unos contenidos que habitualmente no se presentan en investigaciones doctorales tradicionales –lo que permite afrontar nuevos cambios metodológicos, e imprimir un punto de partida para el desarrollo de futuras investigaciones o de otros posibles caminos emergentes–. Así, el discurso se impregna de nuevos referentes teóricos dentro de una misma mitología común (la del estrato). Un tema abordado con claves híbridas, es decir, con estudios selectivos y escritos coleccionados –analizados a partir de antecedentes encontrados y consolidados–, combinados con interpretaciones subyacentes en la arquitectura contemporánea –que pueden todavía encontrarse en fase experimental–. Una investigación que muestra la adaptación, la evolución y el cambio de la definición de "estrato arquitectónico", así como de su apariencia, utilización y aplicación a lo largo del tiempo, consecuencia de las nuevas necesidades y/o de las nuevas bases ideológicas ocasionadas por nuevos descubrimientos. Estratos arquitectónicos que dotan al espacio de profundidad –desde la bidimensionalidad– mediante la superposición de planos paralelos hacia la construcción de una nueva experiencia de estratificación fenomenológica. Estratos que generan estímulos y cambian su materialidad –de opacos a (en)tramados– creando apariencias y produciendo diversos efectos, para posteriormente exfoliarse y convertirse en estratos habitables. Estratos capturadores del espacio-tiempo, o de las dinámicas internas. Llegando incluso, con un último giro, a la era digital, donde el estrato informacional –que continua siendo independiente, autónomo y diverso, y que puede ser modificado, manipulado, suprimido o activable sin alterar el conjunto–, propicia obtener sistemas flexibles, relacionales, capaces de mutar o adaptarse, asociados a distintos niveles de organización dispositiva, que impulsan acciones y hacen emerger lógicas proyectuales. Estratos que surgen de forma elaborada o espontánea en el territorio urbano o natural (ciudad sobre ciudad, suelo sobre suelo), que se aplican extendiendo e hibridando el territorio (paisajes operativos), que son replanteados artificialmente como mecanismos edificatorios según las exigencias existentes (estratos programáticos, capas especializadas), y que se implantan como capas/layers en los programas informáticos utilizados como herramientas de diseño (multicapas, sistemas de intercambio informacional). Un trabajo que se estructura de manera multicapa lo que permite recorrer la tesis como un mapa de secuencias, saltar entre estratos de información, o seleccionar lecturas según intereses de pensamiento o acción arquitectónica. En consecuencia, una investigación sobre el "estrato arquitectónico" que conecta diversas disciplinas, que recopila distintos posicionamientos teórico/prácticos –lo que implica la introducción de parámetros y datos vivos–, y afronta un posicionamiento estratégico que vuelve a poner en valor el estrato arquitectónico –partiendo de estrategias formales que se han transformado en estrategias experimentales/operativas (a medida que el entorno se ha ido complejizando), siguiendo una estrategia conceptual e intelectual contemporánea, propia y específica–. ABSTRACT This PhD thesis is based on the research of "architectural stratum" using concepts, logical and synopsis as organizational, linked and overlapping points, which give way to a proactive framework that can be articulated and independent simultaneously. A situation that, faced with new challenges, aims to go beyond a strict definition of stratum or their preconceived notion described from the superposition of different materials. All this in order to reveal the different profiles of stratum and stratification. To do this, it opens and widens the field of project/process study, blurring the boundaries between disciplines –geology, philosophy, technology, architecture–. And, at the same time, a cartography of the architectural stratum is constructed, that associates with: descriptor taxonomy, new formulations, thoughts of recognizable and/or rescued characters, –as Rowe/Slutzky, Smithson, Parent/Virilio, Koolhaas, MVRDV, etc.–, and finally, a new project and operational logics referred to stratum, which merge complex knowledge. A content not usually presented in traditional doctoral research –which can face new methodological changes, and creates a starting point for future research or other possible emerging paths–. Thus, the work is imbued with new theoretical framework within a common mythology (stratum’s myth). An issue addressed with hybrid keys, that is, with selective studies and collected writings –analyzed starting from found and consolidated backgrounds–, combined with underlying performances on contemporary architecture –which can still be in experimental phase–. A research that shows adaptation, evolution and change of the definition of "architectural stratum", as well as their appearance, use and application throughout time, result of the new requirements and/or the new ideological foundations caused by new discoveries. Architectural strata that give depth to space –from two-dimensionality– by overlapping parallel planes towards the construction of a new experience of phenomenological stratification. Strata that generate stimuli and change their materiality –from opaque to lattice– creating appearances and producing various effects, for later exfoliating and becoming habitable strata. Strata that capture space-time or internal dynamics. Even reaching, with a final twist, the digital age, where the informational stratum –which remains independent, autonomous and diverse, and can be modified, manipulated, deleted or activated without altering the whole–, contribute to obtaining flexible, relational systems, able to mutate or adapt, associated with different levels of regulatory organization, that drive actions and make emerge project logics. Strata that arise elaborately or spontaneously in urban or natural territory (city upon city, floor upon floor), which apply expanding and hybridizing the territory (operational landscapes), which are artificially restated as building mechanisms according to existing requirements (strata program, specialized layers), which are implemented as layers in the software used as design tools (multilayer, systems of informational interchange). A work that is structured in a multi-layered way, which allows explore the thesis as a sequence map, jump between layers of information, or select readings according to an interest in thought or architectural action. Therefore, an investigation into the "architectural stratum" that connects different disciplines, which collects different theoretical/practical positions –which implies the introduction of live parameters and data– and faces a strategic positioning returning to value the architectural stratum –based on formal strategies that have become experimental/operational strategies (as the environment has become more complex), following a conceptual, intellectual, contemporary, own specific strategy–.
Resumo:
The refractive index and extinction coefficient of chemical vapour deposition grown graphene are determined by ellipsometry analysis. Graphene films were grown on copper substrates and transferred as both monolayers and bilayers onto SiO2/Si substrates by using standard manufacturing procedures. The chemical nature and thickness of residual debris formed after the transfer process were elucidated using photoelectron spectroscopy. The real layered structure so deduced has been used instead of the nominal one as the input in the ellipsometry analysis of monolayer and bilayer graphene, transferred onto both native and thermal silicon oxide. The effect of these contamination layers on the optical properties of the stacked structure is noticeable both in the visible and the ultraviolet spectral regions, thus masking the graphene optical response. Finally, the use of heat treatment under a nitrogen atmosphere of the graphene-based stacked structures, as a method to reduce the water content of the sample, and its effect on the optical response of both graphene and the residual debris layer are presented. The Lorentz-Drude model proposed for the optical response of graphene fits fairly well the experimental ellipsometric data for all the analysed graphene-based stacked structures.