Desarrollo de conglomerantes basados en hipótesis constructivas de pirámides egipcias del Reino Antiguo

En la presente tesis doctoral se revisan las principales hipótesis que intentan aclarar los procesos constructivos llevados a cabo para edificar las pirámides egipcias de las Dinastías III y IV, organizándose dichas teorías desde el punto de vista de los posibles materiales constituyentes. La investigación se ha centrado en la hipótesis heterodoxa que propone, como medio para ejecutar estas construcciones, la manufactura completa de la pirámide con piedra caliza conglomerada. Con este fin, se profundiza en artículos que tienen por objeto el análisis de muestras de material de estos monumentos, de piedras calizas naturales y de piedras calizas geopoliméricas, con objeto de determinar si la hipótesis constructiva mencionada es viable. Tomando como referencia la hipótesis constructiva estudiada, se adicionan morteros de cal aérea con carbonato de sodio (natrón) y metacaolín, analizando posteriormente las nuevas características de estos conglomerantes. El cementante descrito en la teoría constructiva se enmarca dentro de la química y tecnología de los polímeros sintéticos inorgánicos activados alcalinamente, también denominados geopolímeros. Se desarrolla una primera mezcla basada en los datos extraídos de la investigación precedente. Posteriormente, se realizan varios grupos de mezclas, en las que se parte de unas proporciones iniciales correspondientes al geopolímero teórico de la hipótesis constructiva. Sobre dichas proporciones se realizan incrementos en la cantidad de cal, y los productos obtenidos son ensayados, tomando datos de: dureza Shore C, velocidad de ultrasonidos, densidades, resistencia a compresión y a flexión, difracción de rayos X, análisis térmicos y microscopía electrónica de barrido. Los resultados derivados de introducir las adiciones, en las proporciones estudiadas, mejoran notablemente algunas características de los morteros de cal convencionales. ABSTRACT In the present PhD thesis the main hypotheses about the construction processes to build the Egyptian pyramids of Dynasties III and IV are reviewed. These theories are addressed from the point of view of their possible constituent materials. The research focuses on the heterodox hypothesis that proposes, as a means to perform these constructions, the complete manufacturing of the pyramid with limestone conglomerate. In this regard, a state of the art is set on the analysis of samples of material of these monuments, natural limestone and limestone geopolymeric, to determine if the constructive hypothesis is viable. Using this constructive hypothesis as a reference, aerial lime mortars are added with sodium carbonate (natron) and metakaolin, and the new characteristics of these resulting binders are then analyzed. The cementing described in the constructive theory belongs to the chemistry and the technology of synthetic inorganic alkali-activated polymers, also called geopolymer. Based on data obtained from previous research, a first mix is prepared. Subsequently, several groups of mixes are made, starting from theoretical initial ratios corresponding to the geopolymer that was presumably used in the constructive hypothesis. Increments in the amount of lime are made upon such proportion, and the resulting products are tested for data collection about: Shore C hardness, ultrasound velocity, densities, compressive and flexural strength, X-ray diffraction, thermal analysis and scanning electron microscopy. The results allow to conclude that, if in the studied proportions, additions improve significantly some of the characteristics of conventional lime mortars.

Estimación de la resistencia de estructuras de hormigón armado reforzadas a cortante mediante FRP

El empleo de refuerzos de FRP en vigas de hormigón armado es cada vez más frecuente por sus numerosas ventajas frente a otros métodos más tradicionales. Durante los últimos años, la técnica FRP-NSM, consistente en introducir barras de FRP sobre el recubrimiento de una viga de hormigón, se ha posicionado como uno de los mejores métodos de refuerzo y rehabilitación de estructuras de hormigón armado, tanto por su facilidad de montaje y mantenimiento, como por su rendimiento para aumentar la capacidad resistente de dichas estructuras. Si bien el refuerzo a flexión ha sido ampliamente desarrollado y estudiado hasta la fecha, no sucede lo mismo con el refuerzo a cortante, debido principalmente a su gran complejidad. Sin embargo, se debería dedicar más estudio a este tipo de refuerzo si se pretenden conservar los criterios de diseño en estructuras de hormigón armado, los cuales están basados en evitar el fallo a cortante por sus consecuencias catastróficas Esta ausencia de información y de normativa es la que justifica esta tesis doctoral. En este pro-yecto se van a desarrollar dos metodologías alternativas, que permiten estimar la capacidad resistente de vigas de hormigón armado, reforzadas a cortante mediante la técnica FRP-NSM. El primer método aplicado consiste en la implementación de una red neuronal artificial capaz de predecir adecuadamente la resistencia a cortante de vigas reforzadas con este método a partir de experimentos anteriores. Asimismo, a partir de la red se han llevado a cabo algunos estudios a fin de comprender mejor la influencia real de algunos parámetros de la viga y del refuerzo sobre la resistencia a cortante con el propósito de lograr diseños más seguros de este tipo de refuerzo. Una configuración óptima de la red requiere discriminar adecuadamente de entre los numerosos parámetros (geométricos y de material) que pueden influir en el compor-tamiento resistente de la viga, para lo cual se han llevado a cabo diversos estudios y pruebas. Mediante el segundo método, se desarrolla una ecuación de proyecto que permite, de forma sencilla, estimar la capacidad de vigas reforzadas a cortante con FRP-NSM, la cual podría ser propuesta para las principales guías de diseño. Para alcanzar este objetivo, se plantea un pro-blema de optimización multiobjetivo a partir de resultados de ensayos experimentales llevados a cabo sobre vigas de hormigón armado con y sin refuerzo de FRP. El problema multiobjetivo se resuelve mediante algoritmos genéticos, en concreto el algoritmo NSGA-II, por ser más apropiado para problemas con varias funciones objetivo que los métodos de optimización clásicos. Mediante una comparativa de las predicciones realizadas con ambos métodos y de los resulta-dos de ensayos experimentales se podrán establecer las ventajas e inconvenientes derivadas de la aplicación de cada una de las dos metodologías. Asimismo, se llevará a cabo un análisis paramétrico con ambos enfoques a fin de intentar determinar la sensibilidad de aquellos pa-rámetros más sensibles a este tipo de refuerzo. Finalmente, se realizará un análisis estadístico de la fiabilidad de las ecuaciones de diseño deri-vadas de la optimización multiobjetivo. Con dicho análisis se puede estimar la capacidad resis-tente de una viga reforzada a cortante con FRP-NSM dentro de un margen de seguridad espe-cificado a priori. ABSTRACT The use of externally bonded (EB) fibre-reinforced polymer (FRP) composites has gained acceptance during the last two decades in the construction engineering community, particularly in the rehabilitation of reinforced concrete (RC) structures. Currently, to increase the shear resistance of RC beams, FRP sheets are externally bonded (EB-FRP) and applied on the external side surface of the beams to be strengthened with different configurations. Of more recent application, the near-surface mounted FRP bar (NSM-FRP) method is another technique successfully used to increase the shear resistance of RC beams. In the NSM method, FRP rods are embedded into grooves intentionally prepared in the concrete cover of the side faces of RC beams. While flexural strengthening has been widely developed and studied so far, the same doesn´t occur to shearing strength mainly due to its great complexity. Nevertheless, if design criteria are to be preserved more research should be done to this sort of strength, which are based on avoiding shear failure and its catastrophic consequences. However, in spite of this, accurately calculating the shear capacity of FRP shear strengthened RC beams remains a complex challenge that has not yet been fully resolved due to the numerous variables involved in the procedure. The objective of this Thesis is to develop methodologies to evaluate the capacity of FRP shear strengthened RC beams by dealing with the problem from a different point of view to the numerical modeling approach by using artificial intelligence techniques. With this purpose two different approaches have been developed: one concerned with the use of artificial neural networks and the other based on the implementation of an optimization approach developed jointly with the use of artificial neural networks (ANNs) and solved with genetic algorithms (GAs). With these approaches some of the difficulties concerned regarding the numerical modeling can be overcome. As an alternative tool to conventional numerical techniques, neural networks do not provide closed form solutions for modeling problems but do, however, offer a complex and accurate solution based on a representative set of historical examples of the relationship. Furthermore, they can adapt solutions over time to include new data. On the other hand, as a second proposal, an optimization approach has also been developed to implement simple yet accurate shear design equations for this kind of strengthening. This approach is developed in a multi-objective framework by considering experimental results of RC beams with and without NSM-FRP. Furthermore, the results obtained with the previous scheme based on ANNs are also used as a filter to choose the parameters to include in the design equations. Genetic algorithms are used to solve the optimization problem since they are especially suitable for solving multi-objective problems when compared to standard optimization methods. The key features of the two proposed procedures are outlined and their performance in predicting the capacity of NSM-FRP shear strengthened RC beams is evaluated by comparison with results from experimental tests and with predictions obtained using a simplified numerical model. A sensitivity study of the predictions of both models for the input parameters is also carried out.

Manufacturing of self-passivating tungsten based alloys by different powder metallurgical routes

Self-passivating tungsten based alloys will provide a major safety advantage compared to pure tungsten when used as first wall armor of future fusion reactors, due to the formation of a protective oxide layer which prevents the formation of volatile and radioactive WO3 in case of a loss of coolant accident with simultaneous air ingress. Bulk WCr10Ti2 alloys were manufactured by two different powder metallurgical routes: (1) mechanical alloying (MA) followed by hot isostatic pressing (HIP) of metallic capsules, and (2) MA, compaction, pressureless sintering in H2 and subsequent HIPing without encapsulation. Both routes resulted in fully dense materials with homogeneous microstructure and grain sizes of 300 nm and 1 μm, respectively. The content of impurities remained unchanged after HIP, but it increased after sintering due to binder residue. It was not possible to produce large samples by route (2) due to difficulties in the uniaxial compaction stage. Flexural strength and fracture toughness measured on samples produced by route (1) revealed a ductile-to-brittle-transition temperature (DBTT) of about 950 °C. The strength increased from room temperature to 800 °C, decreasing significantly in the plastic region. An increase of fracture toughness is observed around the DBTT.

The effects of tantalum addition on the microtexture and mechanical behaviour of tungsten for ITER applications

Tungsten (W) and its alloys are very promising materials for producing plasma-facing components (PFCs) in the fusion power reactors of the near future, even as a structural part in them. However, whereas the properties of pure tungsten are suitable for a PFC, its structural applications are still limited due to its low toughness, ductile to brittle transition temperature and recrystallization behaviour. Therefore, many efforts have been made to improve its performance by alloying tungsten with other elements. Hence, in this investigation, the thermo-mechanical performance of two new tungsten-tantalum materials has been evaluated. Materials with We5wt.%Ta and We15wt.%Ta were processed by mechanical alloying (MA) and later consolidation by hot isostatic pressing (HIP), with distinct settings for each composition. Thus, it was possible to determine the relationship between the microstructure and the addition of Ta with the macroscopic mechanical properties. These were measured by means of hardness, flexural strength and fracture toughness, in the temperature range of 300e1473 K. The microstructure and the fracture surfaces features of the tested materials were analysed by Field Emission Scanning Electron Microscopy (FESEM).

Electro-optical characterization of IC compatible microcantilevers

The aim of this work is to simulate and optically characterize the piezoelectric performance of complementary metal oxide semiconductor (CMOS) compatible microcantilevers based on aluminium nitride (AlN) and manufactured at room temperature. This study should facilitate the integration of piezoelectric micro-electro-mechanical systems (MEMS) such as microcantilevers, in CMOS technology. Besides compatibility with standard integrated circuit manufacturing procedures, low temperature processing also translates into higher throughput and, as a consequence, lower manufacturing costs. Thus, the use of the piezoelectric properties of AlN manufactured by reactive sputtering at room temperature is an important step towards the integration of this type of devices within future CMOS technology standards. To assess the reliability of our fabrication process, we have manufactured arrays of free-standing microcantilever beams of variable dimension and studied their piezoelectric performance. The characterization of the first out-of-plane modes of AlN-actuated piezoelectric microcantilevers has been carried out using two optical techniques: laser Doppler vibrometry (LDV) and white light interferometry (WLI). In order to actuate the cantilevers, a periodic chirp signal in certain frequency ranges was applied between the device electrodes. The nature of the different vibration modes detected has been studied and compared with that obtained by a finite element model based simulation (COMSOL Multiphysics), showing flexural as well as torsional modes. The correspondence between theoretical and experimental data is reasonably good, probing the viability of this high throughput and CMOS compatible fabrication process. To complete the study, X-ray diffraction as well as d33 piezoelectric coefficient measurements were also carried out.