20 resultados para SONIC-SPRAY IONIZATION
Resumo:
The application of a recently developed model of sonic anemometers measuring process has revealed that these sensors cannot be considered as absolute ones when measuring spectral characteristics of turbulent wind speed since it is demonstrated that the ratios of measured to real spectral density functions depend on the composition and temperature of the considered planetary atmosphere. The new model of the measuring process of sonic anemometers is applied to describe the measuring characteristics of these sensors as fluid/flow dependent (against the traditional hypothesis of fluid/flow independence) and hence dependent on the considered planetary atmosphere. The influence of fluid and flow characteristics (quantified via the Mach number of the flow) and the influence of the design parameters of sonic anemometers (mainly represented by time delay between pulses shots and geometry) on turbulence measurement are quantified for the atmospheres of Mars, Jupiter, and Earth. Important differences between the behavior of these sensors for the same averaged wind speed in the three considered atmospheres are detected in terms of characteristics of turbulence measurement as well as in terms of optimum values of anemometer design parameters for application on the different considered planetary atmospheres. These differences cannot be detected by traditional models of sonic anemometer measuring process based on line averaging along the sonic acoustic paths.
Resumo:
In this paper, a model of the measuring process of sonic anemometers with more than one measuring path is presented. The main hypothesis of the work is that the time variation of the turbulent speed field during the sequence of pulses that produces a measure of the wind speed vector affects the measurement. Therefore, the previously considered frozen flow, or instantaneous averaging, condition is relaxed. This time variation, quantified by the mean Mach number of the flow and the time delay between consecutive pulses firings, in combination with both the full geometry of sensors (acoustic path location and orientation) and the incidence angles of the mean with speed vector, give rise to significant errors in the measurement of turbulence which are not considered by models based on the hypothesis of instantaneous line averaging. The additional corrections (relative to the ones proposed by instantaneous line-averaging models) are strongly dependent on the wave number component parallel to the mean wind speed, the time delay between consecutive pulses, the Mach number of the flow, the geometry of the sensor and the incidence angles of mean wind speed vector. Kaimal´s limit k W1=1/l (where k W1 is the wave number component parallel to mean wind speed and l is the path length) for the maximum wave numbers from which the sonic process affects the measurement of turbulence is here generalized as k W1=C l /l, where C l is usually lesser than unity and depends on all the new parameters taken into account by the present model.
Resumo:
In this paper a model for the measuring process of sonic anemometers (ultrasound pulse based) is presented. The differential equations that describe the travel of ultrasound pulses are solved in the general case of non-steady, non-uniform atmospheric flow field. The concepts of instantaneous line-average and travelling pulse-referenced average are established and employed to explain and calculate the differences between the measured turbulent speed (travelling pulse-referenced average) and the line-averaged one. The limit k1l=1 established by Kaimal in 1968, as the maximum value which permits the neglect of the influence of the sonic measuring process on the measurement of turbulent components is reviewed here. Three particular measurement cases are analysed: A non-steady, uniform flow speed field, a steady, non-uniform flow speed field and finally an atmospheric flow speed field. In the first case, for a harmonic time-dependent flow field, Mach number, M (flow speed to sound speed ratio) and time delay between pulses have revealed themselves to be important parameters in the behaviour of sonic anemometers, within the range of operation. The second case demonstrates how the spatial non-uniformity of the flow speed field leads to an influence of the finite transit time of the pulses (M≠0) even in the absence of non-steady behaviour of the wind speed. In the last case, a model of the influence of the sonic anemometer processes on the measurement of wind speed spectral characteristics is presented. The new solution is compared to the line-averaging models existing in the literature. Mach number and time delay significantly distort the measurement in the normal operational range. Classical line averaging solutions are recovered when Mach number and time delay between pulses go to zero in the new proposed model. The results obtained from the mathematical model have been applied to the calculation of errors in different configurations of practical interest, such as an anemometer located on a meteorological mast and the transfer function of a sensor in an atmospheric wind. The expressions obtained can be also applied to determine the quality requirements of the flow in a wind tunnel used for ultrasonic anemometer calibrations.
Resumo:
This work presents a comprehensive optical characterization of Zn1−xMgxO thin films grown by spray pyrolysis (SP). Absorption measurements show the high potential of this technique to tune the bandgap from 3.30 to 4.11 eV by changing the Mg acetate content in the precursor solution, leading to a change of the Mg-content ranging from 0 up to 35%, as measured by transmission electron microscopy-energy dispersive x-ray spectroscopy. The optical emission of the films obtained by cathodoluminescence and photoluminescence spectroscopy shows a blue shift of the peak position from 3.26 to 3.89 eV with increasing Mg incorporation, with a clear excitonic contribution even at high Mg contents. The linewidth broadening of the absorption and emission spectra as well as the magnitude of the observed Stokes shift are found to significantly increase with the Mg content. This is shown to be related to both potential fluctuations induced by pure statistical alloy disorder and the presence of a tail of band states, the latter dominating for medium Mg contents. Finally, metal–semiconductor–metal photodiodes were fabricated showing a high sensitivity and a blue shift in the cut-off energy from 3.32 to 4.02 eV, i.e., down to 308 nm. The photodiodes present large UV/dark contrast ratios (102 − 107), indicating the viability of SP as a growth technique to fabricate low cost (Zn, Mg)O-based UV photodetectors reaching short wavelengths.
Resumo:
This article addresses the problem of spray vaporization and combustion in axisymmetric opposed-jet configurations involving a stream of hot air counterflowing against a stream of nitrogen carrying a spray of fuel droplets. The Reynolds numbers of the jets are assumed to be large, so that mixing of the two streams is restricted to a thin mixing layer that separates the counterflowing streams. The evolution of the droplets in their feed stream from the injection location is seen to depend fundamentally on the value of the droplet Stokes number, St, defined as the ratio of the droplet acceleration time to the mixing layer strain time close to the stagnation point. Two different regimes of spray vaporization and combustion can be identified depending on the value of St. For values of St below a critical value, equal to 1/4 for dilute sprays with small values of the spray liquid mass loading ratio, the droplets decelerate to approach the gas stagnation plane with a vanishing axial velocity. In this case, the droplets located initially near the axis reach the mixing layer, where they can vaporize due to the heat received from the hot air, producing fuel vapor that can burn with the oxygen in a diffusion flame located on the air side of the mixing layer. The character of the spray combustion is different for values of St of order unity, because the droplets cross the stagnation plane and move into the opposing air stream, reaching distances that are much larger than the mixing layer thickness before they turn around. The vaporization of these crossing droplets, and also the combustion of the fuel vapor generated by them, occur in the hot air stream, without significant effects of molecular diffusion, generating a vaporization-assisted nonpremixed flame that stands on the air side outside the mixing layer. Separate formulations will be given below for these two regimes of combustion, with attention restricted to the near-stagnation-point region, where the solution is self-similar and all variables are only dependent on the distance to the stagnation plane. The resulting formulations display a reduced number of controlling parameters that effectively embody dependences of the structure of the spray flame on spray dilution, droplet inertia, and fuel preferential diffusion. Sample solutions are given for the limiting cases of pure vaporization and of infinitely fast chemistry, with the latter limit formulated in terms of chemistry-free coupling functions that allow for general nonunity Lewis numbers of the fuel vapor.