Analysis and optimization of propagation losses in LiNbO3 optical waveguides produced by swift heavy-ion irradiation

The propagation losses (PL) of lithium niobate optical planar waveguides fabricated by swift heavy-ion irradiation (SHI), an alternative to conventional ion implantation, have been investigated and optimized. For waveguide fabrication, congruently melting LiNbO3 substrates were irradiated with F ions at 20 MeV or 30 MeV and fluences in the range 1013–1014 cm−2. The influence of the temperature and time of post-irradiation annealing treatments has been systematically studied. Optimum propagation losses lower than 0.5 dB/cm have been obtained for both TE and TM modes, after a two-stage annealing treatment at 350 and 375∘C. Possible loss mechanisms are discussed.

Migration to an a on.line laboratory in mechanical engineering. The case of a cam follower design practice.

The European Higher Education Area (EHEA) has leaded to a change in the way the subjects are taught. One of the more important aspects of the EHEA is to support the autonomous study of the students. Taking into account this new approach, the virtual laboratory of the subject Mechanisms of the Aeronautical studies at the Technical University of Madrid is being migrated to an on-line scheme. This virtual laboratory consist on two practices: the design of cam-follower mechanisms and the design of trains of gears. Both practices are software applications that, in the current situation, need to be installed on each computer and the students carry out the practice at the computer classroom of the school under the supervision of a teacher. During this year the design of cam-follower mechanisms practice has been moved to a web application using Java and the Google Development Toolkit. In this practice the students has to design and study the running of a cam to perform a specific displacement diagram with a selected follower taking into account that the mechanism must be able to work properly at high speed regime. The practice has maintained its objectives in the new platform but to take advantage of the new methodology and try to avoid the inconveniences that the previous version had shown. Once the new practice has been ready, a pilot study has been carried out to compare both approaches: on-line and in-lab. This paper shows the adaptation of the cam and follower practice to an on-line methodology. Both practices are described and the changes that has been done to the initial one are shown. They are compared and the weak and strong points of each one are analyzed. Finally we explain the pilot study carried out, the students impression and the results obtained.

Meteocean Influence on Inland and Coastal Floods in the East of Spain

The Santa Irene flood, at the end of October 1982, is one of the most dramatically and widely reported flood events in Spain. Its renown is mainly attributable to the collapse of the Tous dam, but its main message is to be the paradigm of the incidence of the maritime/littoral weather and its temporal sea-level rise on the coastal plains inland floods. The Santa Irene flood was attributable to a meteorological phenomenon known as gota fría (cold drop), a relatively frequent and intense rainy phenomenon on the Iberian Peninsula, particularly on the Spanish E to SE inlands and coasts. There are some circumstances that can easily come together to unleash the cold drop there: cold and dry polar air masses coming onto the whole Iberian Peninsula and the north of Africa, high sea-water temperatures, and low atmospheric pressure (cyclone) areas in the western Mediterranean basin; these circumstances are quite common during the autumn and, as it happens, in other places around the world (E/SE Africa). Their occurrence, however, shows a great space-temporal variability (in a similar way to hurricanes on Caribbean and western North Atlantic areas or also in a similar way to typhoons). In fact, all of these are equivalent, although different, phenomena, able to have a different magnitude each time. This paper describes the results of a detailed analysis and reflection about this cold drop phenomenon as a whole, on the generation of its rains, and on the different natures and consequences of its flood. This paper also explains the ways in which the nearby maritime weather and the consequential sea level govern floods on different zones of any hydrographical basin. The Santa Irene case can be considered as a paradigm to explain the influence of nearby maritime climatic conditions on flooding phenomena not only in coastal but also in upward inland areas.

Thermal and mechanical effects of different excitation modes based on low frequency laser modulation in optical hyperthermia

The low frequency modulation of the laser source (menor que30KHz) allows the generation of a pulsed signal that intermittently excites the gold nanorods. The temperature curves obtained for different frequencies and duty cycles of modulation but with equal average power and identical laser parameters, show that the thermal behavior in continuous wave and modulation modes is the same. However, the cell death experiments suggest that the percentage of death is higher in the cases of modulation. This observation allows us to conclude that there are other effects in addition to temperature that contribute to the cellular death. The mechanical effects like sound or pressure waves are expected to be generated from thermal expansion of gold nanorods. In order to study the behavior and magnitude of these processes we have developed a measure device based on ultrasound piezoelectric receivers (25KHz) and a lock-in amplifier that is able to detect the sound waves generated in samples of gold nanorods during laser irradiation providing us a voltage result proportional to the pressure signal. The first results show that the pressure measurements are directly proportional to the concentration of gold nanorods and the laser power, therefore, our present work is focused on determine the real influence of these effects in the cell death process.

FRe building technological products

Nowadays "Flood Resilient (FRe) Building Technological Products" is an undefined concept, and concerned FRe solutions cannot be even easily identified. There is an interest in offering an identification and classification of the referred products, since it will be useful for stakeholders and populations at flood risk for adopting the most adequate protections when facing floods. There are many barriers for the implementation of "FRe building technological products", and particularly their standardization is still a major challenge. To put into contact such solutions with final customers, it appears necessary to protocolize them all. The classification effort achieved in this document shall be considered as a necessary preliminary step in order to open the road to the market to FRe building technological solutions.

Looking for a more comprehensive approach

The necessity/convenience for improving accuracy in determining the flood frequency is widely accepted further than among hydrologists, and is increasingly deepened in relationship with the statement of different thresholds related to the respective management systems. And both Scientific and Management Communities fully accept the necessity of living with determined levels of flood risk. Most of the approaches for “Advancing Methods” improving concentrate on the statistical ways, even since Climate in fact is not a Stationary process. The question is here reflected since the SMARTeST research and final highlights, policy and recommendations. The paper looks at a better agreement between Hydrology and the whole Climate as the result of the Global Thermal Machine and takes mainly into account a historical approach, trying to show the necessity of a wider collection and analysis of climate data for statistical approaches.

Functional and environmental design of detached, low crest level breakwaters

In this article we research the design of detached breakwaters, a type of coastal defence work designed to combat erosion on beaches in a stable, sustainable fashion. Our aim is to formulate a functional and environmental (nonstructural) method of design that defines the fundamental characteristics of a detached breakwater as a function of the desired effect on the coast whilst meeting social demands and preserving or improving the quality of the littoral environment. We aim to make this method generally applicable by considering relations between variables of different natures (climatic, geomorphologic, and geometric) influencing the changes experienced on the coast after the detached breakwater has been built. We carried out the study of the relations between the different variables on the data from 19 actual, existing detached breakwaters on the Spanish Mediterranean coastline, and we followed a methodology based on the implementation of nondimensional monomials and on a search for relations of dependency between them. Finally, we discussed the results obtained and came up with a proposal for a design method that uses some of the graphic relations found between the variables studied and that achieves the main objective. For example, a case of a detached breakwater’s geometric presizing is solved as a practical demonstration of how the method is applied. La investigación que se presenta en este artículo aborda el diseño de los diques exentos, por constituir estos un tipo de obras de defensa costera con el que poder luchar de una forma estable y sostenible contra muchos de los problemas de erosión que existen en las playas. El objetivo principal de este trabajo es la formulación de un método de diseño funcional y ambiental (no estructural) que permita definir las características fundamentales de un dique exento en función del efecto que se quiera inducir en la costa, satisfaciendo las demandas sociales y preservando o mejorando la calidad del medio ambiente litoral. Además, se busca la aplicabilidad general del método mediante la consideración de relaciones entre variables de distinta naturaleza (climáticas, geomorfológicas y geométricas) que tienen influencia en los cambios que se experimentan en la costa tras la construcción del dique exento. El estudio de las relaciones entre las distintas variables se realiza sobre los datos de una base de diecinueve diques exentos reales, existentes en el litoral mediterráneo español, y sigue una metodología basada en el planteamiento de monomios adimensionales y en la búsqueda de relaciones de dependencia entre ellos. Finalmente, la discusión de los resultados obtenidos conduce a la propuesta de un método de diseño que utiliza algunas de las relaciones graficas encontradas entre las variables estudiadas y con el que se consigue el objetivo principal anteriormente expuesto. Para demostrar la aplicación práctica del método se resuelve un caso de predimensionamiento geométrico de un dique exento a modo de ejemplo.

Coastal floods and decadal changes: the climate factor

Observation has widely shown for nearly all last century that the Spanish (Dynamic) Maritime Climate was following around 10 to 11 year cycles in its most significant figure, wind wave, despite it being better to register cycles of 20 to 22 years, in analogical way with the semi-diurnal and diurnal cycles of Cantabrian tides. Those cycles were soon linked to sun activity and, at the end of the century, the latter was related to the Solar System evolution. We know now that waves and storm surges are coupled and that (Dynamic) Maritime Climate forms part of a more complex “Thermal Machine” including Hydrological cycle. The analysis of coastal floods could so facilitate the extension of that experience. According to their immediate cause, simple flood are usually sorted out into flash, pluvial, fluvial, groundwater and coastal types, considering the last as caused by sea waters. But the fact is that most of coastal floods are the result of the concomitance of several former simple types. Actually, the several Southeastern Mediterranean coastal flood events show to be the result of the superposition within the coastal zone of flash, fluvial, pluvial and groundwater flood types under boundary condition imposed by the concomitant storm sea level rise. This work shall be regarded as an attempt to clarify that cyclic experience, through an in-depth review of a past flood events in Valencia (Turia and Júcar basins), as in Murcia (Segura’s) as well.

Understanding extreme Spanish coastal flood events

The Santa Irene flood event, at the end of October 1982, is one of the most dramatically widely reported flood events in Spain. Its renown is mainly due to the collapse of the Tous dam, but its main message is to be the paradigm of the incidence of the maritime/littoral weather and its temporal sea level rise by storm surge accompanying rain process on the coastal plains inland floods. Looking at damages the presentation analyzes the adapted measures from the point of view of the aims of the FP7 SMARTeST Project related to the Flood Resilience improvement in urban areas through looking for Technologies, Systems and Tools an appropriate "road to de market".

Looking for a more comprehensive approach

The necessity/convenience for improving accuracy in determining the flood frequency is widely accepted further than among hydrologists, and is increasingly deepened in relationship with the statement of different thresholds related to the respective management systems. And both Scientific and Management Communities fully accept the necessity of living with determined levels of flood risk. Most of the approaches for “Advancing Methods” improving concentrate on the statistical ways, even since Climate in fact is not a Stationary process. The question is here reflected since the SMARTeST research and final highlights, policy and recommendations. The paper looks at a better agreement between Hydrology and the whole Climate as the result of the Global Thermal Machine and takes mainly into account a historical approach, trying to show the necessity of a wider collection and analysis of climate data for statistical approaches.

Photoacoustic effect measurement in aqueous suspensions of gold nanorods caused by low-frequency and low-power near-infrared pulsing laser irradiation

When aqueous suspensions of gold nanorods are irradiated with a pulsing laser (808 nm), pressure waves appear even at low frequencies (pulse repetition rate of 25 kHz). We found that the pressure wave amplitude depends on the dynamics of the phenomenon. For fixed concentration and average laser current intensity, the amplitude of the pressure waves shows a trend of increasing with the pulse slope and the pulse maximum amplitude.We postulate that the detected ultrasonic pressure waves are a sort of shock waves that would be generated at the beginning of each pulse, because the pressure wave amplitude would be the result of the positive interference of all the individual shock waves.

Calculation of the spatial distribution of photovoltaic field by arbitrary 2D ilumination patterns en LiNbO3; application to photovoltaic particle trapping.

Patterns of evanescent photovoltaic field induced by illumination on a surface of lithium niobate (LN) have been calculated and compared with the experimental patterns of nano- and microparticles trapped by dielectrophoretic forces. A tool for this calculation has been developed. Calculo de distribución espacial de campo por efecto fotovoltaico con patrones arbitrarios de iluminación, en LiNbO3

Photovoltaic LiNbO3particles: Applications to Biomedicine/Biophotonics

Recently, a novel method to trap and pattern ensembles of nanoparticles has been proposed and tested. It relies on the photovoltaic (PV) properties of certain ferroelectric crystals such as LiNbO3 [1,2]. These crystals, when suitably doped, develop very high electric fields in response to illumination with light of suitable wavelength. The PV effect lies in the asymmetrical excitation of electrons giving rise to PV currents and associated space-charge fields (photorefractive effect). The field generated in the bulk of the sample propagates to the surrounding medium as evanescent fields. When dielectric or metal nanoparticles are deposited on the surface of the sample the evanescent fields give rise to either electrophoretic or dielectrophoretic forces, depending on the charge state of the particles, that induce the trapping and patterning effects [3,4]. The purpose of this work has been to explore the effects of such PV fields in the biology and biomedical areas. A first work was able to show the necrotic effects induced by such fields on He-La tumour cells grown on the surface of an illuminated iron-doped LiNbO3 crystal [5]. In principle, it is conceived that LiNbO3 nanoparticles may be advantageously used for such biomedical purposes considering the possibility of such nanoparticles being incorporated into the cells. Previous experiments using microparticles have been performed [5] with similar results to those achieved with the substrate. Therefore, the purpose of this work has been to fabricate and characterize the LiNbO3 nanoparticles and assess their necrotic effects when they are incorporated on a culture of tumour cells. Two different preparation methods have been used: 1) mechanical grinding from crystals, and 2) bottom-up sol-gel chemical synthesis from metal-ethoxide precursors. This later method leads to a more uniform size distribution of smaller particles (down to around 50 nm). Fig. 1(a) and 1(b) shows SEM images of the nanoparticles obtained with both method. An ad hoc software taking into account the physical properties of the crystal, particullarly donor and aceptor concentrations has been developped in order to estimate the electric field generated in noparticles. In a first stage simulations of the electric current of nanoparticles, in a conductive media, due to the PV effect have been carried out by MonteCarlo simulations using the Kutharev 1-centre transport model equations [6] . Special attention has been paid to the dependence on particle size and [Fe2+]/[Fe3+]. First results on cubic particles shows large dispersion for small sizes due to the random number of donors and its effective concentration (Fig 2). The necrotic (toxicity) effect of nanoparticles incorporated into a tumour cell culture subjected to 30 min. illumination with a blue LED is shown in Fig.3. For each type of nanoparticle the percent of cell survival in dark and illumination conditions has been plot as a function of the particle dilution factor. Fig. 1a corresponds to mechanical grinding particles whereas 1b and 1c refer to chemically synthesized particles with two oxidation states. The light effect is larger with mechanical grinding nanoparticles, but dark toxicity is also higher. For chemically synthesized nanoparticles dark toxicity is low but only in oxidized samples, where the PV effect is known to be larger, the light effect is appreciable. These preliminary results demonstrate that Fe:LiNbO· nanoparticles have a biological damaging effect on cells, although there are many points that should be clarified and much space for PV nanoparticles optimization. In particular, it appears necessary to determine the fraction of nanoparticles that become incorporated into the cells and the possible existence of threshold size effects. This work has been supported by MINECO under grant MAT2011-28379-C03.

Wettability, polarity and water absorption of Quercus ilex leaves: effect of leaf side and age

Plant trichomes play important protective functions and may have a major influence on leaf surface wettability. With the aim of gaining insight into trichome structure, composition and function in relation to water-plant surface interactions, we analyzed the adaxial and abaxial leaf surface of Quercus ilex L. (holm oak) as model. By measuring the leaf water potential 24 h after the deposition of water drops on to abaxial and adaxial surfaces, evidence for water penetration through the upper leaf side was gained in young and mature leaves. The structure and chemical composition of the abaxial (always present) and adaxial (occurring only in young leaves) trichomes were analyzed by various microscopic and analytical procedures. The adaxial surfaces were wettable and had a high degree of water drop adhesion in contrast to the highly unwettable and water repellent abaxial holm oak leaf sides. The surface free energy, polarity and solubility parameter decreased with leaf age, with generally higher values determined for the abaxial sides. All holm oak leaf trichomes were covered with a cuticle. The abaxial trichomes were composed of 8% soluble waxes, 49% cutin, and 43% polysaccharides. For the adaxial side, it is concluded that trichomes and the scars after trichome shedding contribute to water uptake, while the abaxial leaf side is highly hydrophobic due to its high degree of pubescence and different trichome structure, composition and density. Results are interpreted in terms of water-plant surface interactions, plant surface physical-chemistry, and plant ecophysiology.

A method to obtain the thermal parameters and the photothermal transduction efficiency in an optical hyperthermia device based on laser irradiation of gold nanoparticles

Optical hyperthermia systems based on the laser irradiation of gold nanorods seem to be a promising tool in the development of therapies against cancer. After a proof of concept in which the authors demonstrated the efficiency of this kind of systems, a modeling process based on an equivalent thermal-electric circuit has been carried out to determine the thermal parameters of the system and an energy balance obtained from the time-dependent heating and cooling temperature curves of the irradiated samples in order to obtain the photothermal transduction efficiency. By knowing this parameter, it is possible to increase the effectiveness of the treatments, thanks to the possibility of predicting the response of the device depending on the working configuration. As an example, the thermal behavior of two different kinds of nanoparticles is compared. The results show that, under identical conditions, the use of PEGylated gold nanorods allows for a more efficient heating compared with bare nanorods, and therefore, it results in a more effective therapy.