3 resultados para Soil - Heavy metal contamination
em Universidade Estadual Paulista "Júlio de Mesquita Filho" (UNESP)
Resumo:
Este trabalho tem por objetivo apresentar uma aplicação de métodos geoestatísticos na elaboração de mapas de risco à saúde pública, por meio da identificação de áreas com maior concentração de metais pesados. Foi escolhido o elemento chumbo (Pb), resultante do transporte aéreo ou do carregamento das partículas causado pela lixiviação do solo, em uma região com grande concentração urbana e industrial na Baixada Santista, São Paulo, Brasil. Elaboraram-se mapas das distribuições espaciais desse elemento por intermédio da krigagem ordinária; posteriormente, utilizando-se a krigagem indicativa, identificaram-se as áreas com valores de contaminação do solo superiores aos níveis máximos aceitáveis pelo órgão de controle ambiental do Estado de São Paulo, originando um mapeamento com áreas com maior probabilidade de risco à saúde pública. Os mapas resultantes mostraram-se ferramentas promissoras para auxiliar a tomada de decisão quanto a questões de políticas públicas relacionadas à saúde e ao planejamento ambiental.
Resumo:
Three approaches were applied to evaluate metal contamination in 41 sediment samples from the Santos - São Vicente Estuarine System: normalization to Al, statistical analysis and sediment quality guidelines (SQGs). The results showed increases in the concentrations of Zn, Ni, Pb, Cd, Cr and Hg, which seemed to be associated with human activities. The levels of Al, Fe and Co probably were associated with crustal material or natural weathering processes. About 45% of the samples presented concentrations exceeding TEL-ERL, levels occasionally associated with adverse biological effects. Four of these samples presented concentrations above PEL-ERM, levels frequently associated with adverse biological effects.
Resumo:
The crab Ucides cordatus and the red mangrove Rhizophora mangle are endemic mangrove species and potential bio-accumulators of metals. This study quantified the accumulation of six metals (Cd, Cr, Cu, Hg, Mn and Pb) in different organs (claw muscle, hepatopancreas and gills) of U. cordatus, as well as in different maturation stages of the leaves (buds, green mature, and pre-abscission senescent) of R. mangle. Samples were collected from mangrove areas in Cubatao, state of São Paulo, a heavily polluted region in Brazil. Data for metal contents in leaves were evaluated by one-way ANOVA; while for crabs a factorial ANOVA was used to investigate the effect of different tissues, animal size and the interactions between them. Means were compared by Tukey test at five percent, and the association between the metal concentrations in each crab organ, depending on the size, was evaluated by Pearson's linear correlation coefficient (r). Concentrations of Pb and Hg were undetectable for the different leaf stages and crab tissues, while Cd concentrations were undetectable in the leaf stages. In general, the highest accumulation of metals in R. mangle leaves occurred in pre-abscission senescent and green mature leaves, except for Cu, which was found in the highest concentrations in buds and green mature leaves. For the crab, Cd, Cu, Cr and Mn were present in concentrations above the detection limit, with the highest accumulation in the hepatopancreas, followed by the gills. Cu was accumulated mostly in the gills. Patterns of bioaccumulation between the crab and the mangrove tree differed for each metal, probably due to the specific requirements of each organism for essential metals. However, there was a close and direct relationship between metal accumulation in the mangrove trees and in the crabs feeding on them. Tissues of R. mangle leaves and U. cordatus proved effective for monitoring metals, acting as important bioindicators of mangrove areas contaminated by various metals. (C) 2012 Elsevier B.V. All rights reserved.