A Novel Short-Step Synthesis of New Xanthenedione Derivatives from the Cyclization of 3-Cinnamoyl-2-styrylchromones

Novel (E)-3-aryl-4-benzylidene-8-hydroxy-3,4-dihydro-1 H-xanthene-1,9(2H)-diones are prepared by the cyclization of (E,E)-3-cinnamoyl-5-hydroxy-2-styrylchromones efficiently catalyzed with boron tribromide. The (E,E)-3-cinnamoyl-5-hydroxy-2-styrylchromones are obtained from the Baker–Venkataraman rearrangement of (E,E)-2-acetyl-1,3-phenylene bis(3-phenylacrylate), which is greatly improved under microwave irradiation.

Synthesis of new 1,8-dihydroxy-9h-xanthen-9-ones

XXVth European Colloquium on Heterocyclic Chemistry, Reading, UK, 13 – 17 Agosto de 2012.

New syntheses of potential biologically active xanthones and benzoxanthones

10º Encontro Nacional de Química Orgânica e 1º Simpósio Luso-Brasileiro de Química Orgânica, Lisboa, 4-6 Setembro de 2013.

14, de Jean Echenoz, un récit de guerre à l’épreuve du pathos

14 is a recently published novel by a French contemporary writer, Jean Echenoz. Having the First World War as its core subject, the text covers the main traditional themes of war novels. Its interest, however, does not lie in what it says about the war, but rather in how the war is told. In fact, 14 points out the main horrors of the war, without engaging in pathos. In order to do so, Echenoz resorts to two groups of techniques, whose main purpose is to lighten the dramatic effect of the war scenes depicted. Surprisingly, the result is a text which recounts the crude horrors of war.