Catalytic Asymmetric Transfer Hydrogenation of Imines: Recent Advances
Contribuinte(s) |
Universidad de Alicante. Departamento de Química Orgánica Universidad de Alicante. Instituto Universitario de Síntesis Orgánica Síntesis Asimétrica (SINTAS) |
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Data(s) |
22/09/2016
22/09/2016
01/10/2015
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Resumo |
In this review article recent developments in the asymmetric transfer hydrogenation of imines from 2008 up to today are presented. The main methodology involves either metal-catalyzed procedures in the presence of a chiral ligand or organocatalyzed technologies using a Hantzsch ester and a chiral BINOL-derived phosphoric acid. The most important procedures are collected, paying special attention to the application of this methodology in synthetic organic chemistry. We thank the continued financial support from our Ministerio de Ciencia e Innovación (MICINN; projects CTQ2007-62771/BQU, CTQ2010-20387, CONSOLIDER INGENIO 2010-CDS2007-00006, CTQ2011-24151, CTQ2011-24165), the Ministerio de Economía y Competitividad (MINECO; projects CTQ2013-43446-P, CTQ2014-51912-REDC, CTQ2014-53695-P), FEDER, the Generalitat Valenciana (PROMETEO 2009/039, PROMETEOII/2014/017), and the University of Alicante. |
Identificador |
The Chemical Record. 2015, 15(5): 907-924. doi:10.1002/tcr.201500203 1527-8999 (Print) 1528-0691 (Online) http://hdl.handle.net/10045/58134 10.1002/tcr.201500203 |
Idioma(s) |
eng |
Publicador |
Chemical Society of Japan Wiley-VCH Verlag GmbH & Co. KGaA |
Relação |
http://dx.doi.org/10.1002/tcr.201500203 |
Direitos |
© 2015 The Chemical Society of Japan and Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim info:eu-repo/semantics/openAccess |
Palavras-Chave | #Asymmetric synthesis #Homogeneous catalysis #Hydrogen transfer, imines #Organocatalysis #Química Orgánica |
Tipo |
info:eu-repo/semantics/article |