Reduction of 1,2-dicarbonyl compounds and of their N-phenylimine derivatives by sodium cyanide under aprotic conditions
| Contribuinte(s) |
Universidad de Alicante. Departamento de Química Orgánica Universidad de Alicante. Instituto Universitario de Síntesis Orgánica Nuevos Materiales y Catalizadores (MATCAT) |
|---|---|
| Data(s) |
15/09/2016
15/09/2016
01/12/2015
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| Resumo |
Some aromatic 1,2-dicarbonyl compounds, i.e. 9,10-phenanthrenequinone, acenaphthenequinone and benzil, and their corresponding N-phenyl monoimines, have been reduced, using dry acetonitrile as the solvent, in the presence of sodium cyanide as a reducing agent. Comparative potentiostatic preparative-scale electrolysis is described. The authors gratefully acknowledge the financial support of the University of Alcala – project No. CCG2014/EXP-010. K. Hamrouni thanks the Tunisian Ministry of Science that provided her a grant ‘‘bourse d’alternance’’ as financial support of her stay in Spain. |
| Identificador |
Comptes Rendus Chimie. 2015, 18(12): 1284-1288. doi:10.1016/j.crci.2015.07.007 1631-0748 (Print) 1878-1543 (Online) http://hdl.handle.net/10045/57942 10.1016/j.crci.2015.07.007 |
| Idioma(s) |
eng |
| Publicador |
Elsevier |
| Relação |
http://dx.doi.org/10.1016/j.crci.2015.07.007 |
| Direitos |
© 2015 Académie des sciences. Published by Elsevier Masson SAS. info:eu-repo/semantics/restrictedAccess |
| Palavras-Chave | #Homogeneous electron transfer #Radical anion #Cathode #Superoxide anion #Oxygen #Química Orgánica |
| Tipo |
info:eu-repo/semantics/article |
