Improved mechanical stability of HKUST-1 in confined nanospace


Autoria(s): Casco, Mirian Elizabeth; Fernández-Catalá, Javier; Martinez-Escandell, Manuel; Rodríguez Reinoso, Francisco; Ramos-Fernández, Enrique V.; Silvestre-Albero, Joaquín
Contribuinte(s)

Universidad de Alicante. Departamento de Química Inorgánica

Universidad de Alicante. Instituto Universitario de Materiales

Materiales Avanzados

Data(s)

13/09/2016

13/09/2016

27/07/2015

Resumo

One of the main concerns in the technological application of several metal–organic frameworks (MOFs) relates to their structural instability under pressure (after a conforming step). Here we report for the first time that mechanical instability can be highly improved via nucleation and growth of MOF nanocrystals in the confined nanospace of activated carbons.

Financial support from MINECO projects MAT2013-45008-p and CONCERT Project-NASEMS (PCIN-2013-057) is gratefully acknowledged.

Identificador

Chemical Communications. 2015, 51: 14191-14194. doi:10.1039/C5CC05107J

1359-7345 (Print)

1364-548X (Online)

http://hdl.handle.net/10045/57846

10.1039/C5CC05107J

Idioma(s)

eng

Publicador

Royal Society of Chemistry

Relação

http://dx.doi.org/10.1039/C5CC05107J

Direitos

© Royal Society of Chemistry 2015

info:eu-repo/semantics/openAccess

Palavras-Chave #Mechanical stability #HKUST-1 #Confined nanospace #Química Inorgánica
Tipo

info:eu-repo/semantics/article