Selective hydrogenation by novel composite supported Pd egg-shell catalysts
| Contribuinte(s) |
Universidad de Alicante. Servicios Técnicos de Investigación Materiales Avanzados |
|---|---|
| Data(s) |
13/09/2016
13/09/2016
10/02/2015
|
| Resumo |
Two organic–inorganic mixed phase supports were prepared, comprising an alumina filler and polymers of different chemical nature. Four low loaded Pd catalysts were prepared. Good activities and selectivities were obtained during the hydrogenations of styrene, 1-heptyne and 2,3-butanedione. The catalysts were found to have excellent mechanical properties and could be used in applications needing high attrition resistance and crushing strength. In this sense, processes for fine chemicals using slurry reactors or processes for commodities using long packed beds could advantageously use them. The authors are gratefully indebted to ANPCyT, CONICET, UNL and SECTeI Santa Fe for funding this work. |
| Identificador |
Catalysis Communications. 2015, 61: 72-77. doi:10.1016/j.catcom.2014.12.012 1566-7367 (Print) 1873-3905 (Online) http://hdl.handle.net/10045/57831 10.1016/j.catcom.2014.12.012 |
| Idioma(s) |
eng |
| Publicador |
Elsevier |
| Relação |
http://dx.doi.org/10.1016/j.catcom.2014.12.012 |
| Direitos |
© 2014 Elsevier B.V. info:eu-repo/semantics/restrictedAccess |
| Palavras-Chave | #Pd/composite #Egg-shell catalysts #Selective hydrogenation #Mechanical property improvement |
| Tipo |
info:eu-repo/semantics/article |
