In situ differentiation of labile/inert metal species in Brazilian tropical rivers by means of a time-controlled batch-procedure based on TEPHA resin


Autoria(s): Goveia, Danielle; Lobo, Fabiana A.; Bellin, Iramaia C.; Fraceto, Leonardo F.; Menegario, Amauri A.; Burba, Peter; Rosa, Andre H.
Contribuinte(s)

Universidade Estadual Paulista (UNESP)

Data(s)

20/05/2014

25/10/2016

20/05/2014

25/10/2016

01/01/2011

Resumo

The present study deals with a new analytical procedure based on a cellulose diffusion membrane and immobilised tetraethylene-pentamine-hexaacetate chelator (DM-TEPHA) for an in situ differentiation of labile and inert metal species in aquatic systems. The DM-TEPHA system was prepared by placing TEPHA chelator in pre-purified cellulose bags and in situ applied immersing the system in two Brazilian rivers to study the relative lability of metal species (Cu, Pb, Fe, Mn and Ni) as a function of the time and the quantity of exchanger, respectively. The procedure is simple and enables a new perspective for understanding the complexation, transport, stability and lability of metal species in aquatic systems rich in organic matter.

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Identificador

International Journal of Environmental Analytical Chemistry. Abingdon: Taylor & Francis Ltd, v. 91, n. 13, p. 1296-1309, 2011.

0306-7319

http://hdl.handle.net/11449/187

http://acervodigital.unesp.br/handle/11449/187

10.1080/03067319.2010.484883

WOS:000298154700006

0000-0002-2042-018X

http://dx.doi.org/10.1080/03067319.2010.484883

Idioma(s)

eng

Publicador

Taylor & Francis Ltd

Relação

International Journal of Environmental Analytical Chemistry

Direitos

info:eu-repo/semantics/closedAccess

Palavras-Chave #water #humic substances #lability, metals #aquatic organic matter
Tipo

outro