Structural aspects of reversible molecular oxygen uptake
| Cobertura |
709 - 710 |
|---|---|
| Data(s) |
01/12/1967
|
| Resumo |
The system IrX(CO)[P(C6H5)3]3 in benzene solution adds molecular oxygen reversibly if X is chlorine and irreversibly if X is iodine. The crystal structure of the complex IrIO 2(CO)[P(C6H5)3]2 · CH2Cl2 is reported here and compared with a previous study of the structure of IrClO2(CO)[P(C6H 5)3]2. The O-O bond length is 1.47 ± 0.02 angstroms in the irreversibly oxygenated iodo-compound and 1.30 ± 0.03 angstroms in the reversibly oxygenated chlorocompound. |
| Formato |
application/pdf |
| Identificador |
qt4zj8s0t0 |
| Idioma(s) |
english |
| Publicador |
eScholarship, University of California |
| Direitos |
Attribution (CC BY): http://creativecommons.org/licenses/by/3.0/ |
| Fonte |
McGinnety, JA; Doedens, RJ; & Ibers, JA. (1967). Structural aspects of reversible molecular oxygen uptake. Science, 155(3763), 709 - 710. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/4zj8s0t0 |
| Tipo |
article |
