Aroylhydrazone Cu(II) complexes in keto form: structural characterization and catalytic cctivity towards cyclohexane oxidation
Data(s) |
30/06/2016
30/06/2016
01/04/2016
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Resumo |
The reaction of the Schiff base (3,5-di-tert-butyl-2-hydroxybenzylidene)-2-hydroxybenzohydrazide (H3L) with a copper(II) salt of a base of a strong acid, i.e., nitrate, chloride or sulphate, yielded the mononuclear complexes [Cu(H2L)(NO3)(H2O)] (1), [Cu(H2L)Cl]center dot 2MeOH (2) and the binuclear complex [{Cu(H2L)}(2)(mu-SO4)]center dot 2MeOH (3), respectively, with H2L- in the keto form. Compounds 1-3 were characterized by elemental analysis, Infrared (IR) spectroscopy, Electrospray Ionisation-Mass Spectrometry (ESI-MS) and single crystal X-ray crystallography. All compounds act as efficient catalysts towards the peroxidative oxidation of cyclohexane to cyclohexyl hydroperoxide, cyclohexanol and cyclohexanone, under mild conditions. In the presence of an acid promoter, overall yields (based on the alkane) up to 25% and a turnover number (TON) of 250 (TOF of 42 h(-1)) after 6 h, were achieved. |
Identificador |
Sutradhar, Manas; [et al.] - Aroylhydrazone Cu(II) complexes in keto form: structural characterization and catalytic cctivity towards cyclohexane oxidation. Molecules. ISSN 1420-3049. Vol. 21, Nr. 4, S 425, (2016) 1420-3049 http://hdl.handle.net/10400.21/6277 10.3390/molecules21040425 |
Idioma(s) |
eng |
Publicador |
MDPI AG |
Relação |
info:eu-repo/grantAgreement/FCT/5876/147216/PT PTDC/QEQ-ERQ/1648/2014 PTDC/QEQ-QIN/3967/2014 info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F86067%2F2012/PT 425; http://www.mdpi.com/1420-3049/21/4/425 |
Direitos |
closedAccess |
Palavras-Chave | #O,N,O ligands #Cu(II) complex #X-ray structure #cyclohexane oxidation |
Tipo |
article |