Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation
| Data(s) |
30/06/2016
30/06/2016
2016
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|---|---|
| Resumo |
The highly efficient eco-friendly synthesis of ketones (yields over 99%) from secondary alcohols is achieved by combination of [FeCl2{eta(3)-HC(pz)(3)}] (pz = pyrazol-1-yl) supported on functionalized multi-walled carbon nanotubes and microwave irradiation, in a solvent-free medium. The carbon homoscorpionate iron(II) complex is the first one of this class to be used as catalyst for the oxidation of alcohols. |
| Identificador |
MARTINS, Luisa Margarida Dias Ribeiro de Sousa; [et al.] - Highly efficient and reusable CNT supported iron(II) catalyst for microwave assisted alcohol oxidation. Dalton transactions. ISSN 1477-9226. Vol. 45, Nr. 16, (2016), 6816-6819. 1477-9226 1477-9234 http://hdl.handle.net/10400.21/6276 10.1039/c6dt00514d |
| Idioma(s) |
eng |
| Publicador |
Royal Soc Chemistry |
| Relação |
info:eu-repo/grantAgreement/FCT/5876/147216/PT PTDC/QEQ-ERQ/1648/2014 PTDC/QEQ-QIN/3967/2014 UID/EQU/50020/2013 2013-POCI-01-0145-FEDER-006984 IF/01381/2013/CP1160/CT0007 info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F90883%2F2012/PT http://pubs.rsc.org/en/Content/ArticleLanding/2016/DT/C6DT00514D#!divAbstract |
| Direitos |
closedAccess |
| Palavras-Chave | #Cyclohexane oxidation #Hydrogen-peroxide #Aerobic oxidation #Complexes #XPS #Radicals #FE |
| Tipo |
article |
