Microwave Synthesis of Short-Chained Fluorinated Ionic Liquids and Their Surface Properties


Autoria(s): Breen, John M.; Olejarz, Sonia; Seddon, Kenneth R.
Data(s)

2016

Resumo

Microwave synthesis is shown to be a valuable route to novel fluorinated ionic liquid surfactants. 1-Methyl-3-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)imidazolium iodide was prepared by treatment of 1-methylimidazole with 1-iodo-1H,1H,2H,2H-perfluorohexane in a microwave reactor, and this product underwent anion exchange to yield 1-methyl-3-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)imidazolium nonafluoro-1-butanesulfonate. This catanionic surfactant showed intriguing phase behavior and low surface tension.

Identificador

http://pure.qub.ac.uk/portal/en/publications/microwave-synthesis-of-shortchained-fluorinated-ionic-liquids-and-their-surface-properties(8b10e126-0401-490c-aaf9-594e4e617b86).html

http://dx.doi.org/ 10.1021/acssuschemeng.5b01265

Idioma(s)

eng

Direitos

info:eu-repo/semantics/closedAccess

Fonte

Breen , J M , Olejarz , S & Seddon , K R 2016 , ' Microwave Synthesis of Short-Chained Fluorinated Ionic Liquids and Their Surface Properties ' ACS Sustainable Chemistry & Engineering , vol 4 , no. 2 , pp. 387-391 . DOI: 10.1021/acssuschemeng.5b01265

Tipo

article