Determination of toluene hydrogenation kinetics with neutron diffraction
| Data(s) |
2016
|
|---|---|
| Resumo |
<p>Total neutron scattering has been used to follow the hydrogenation of toluene-d<sub>8</sub> to methylcyclohexane-d<sub>14</sub> over 3 wt% platinum supported on highly ordered mesoporous silica (MCM-41) at 298 K and under 150 mbar D<sub>2</sub> pressure. The detailed kinetic information so revealed indicates that liquid reorganisation inside pores is the slowest step of the whole process. Additionally, the results were compared with the reaction performed under 250 mbar D<sub>2</sub> pressure as well as with toluene-h<sub>8</sub> hydrogenation using D<sub>2</sub> at 150 mbar.</p> |
| Formato |
application/pdf |
| Identificador |
http://dx.doi.org/10.1039/c6cp01494a http://www.scopus.com/inward/record.url?scp=84976866456&partnerID=8YFLogxK |
| Idioma(s) |
eng |
| Direitos |
info:eu-repo/semantics/openAccess |
| Fonte |
Falkowska , M , Chansai , S , Manyar , H G , Gladden , L F , Bowron , D T , Youngs , T G A & Hardacre , C 2016 , ' Determination of toluene hydrogenation kinetics with neutron diffraction ' Physical Chemistry Chemical Physics , vol 18 , no. 26 , pp. 17237-17243 . DOI: 10.1039/c6cp01494a |
| Palavras-Chave | #/dk/atira/pure/subjectarea/asjc/1600/1606 #Physical and Theoretical Chemistry #/dk/atira/pure/subjectarea/asjc/3100 #Physics and Astronomy(all) |
| Tipo |
article |
