Control over the Self-Assembly Modes of PtII Complexes by Alkyl Chain Variation: From Slipped to Parallel π-Stacks


Autoria(s): Allampally, Naveen Kumar; Mayoral, Maria Jose; Chansai, Sarayute; Lagunas, Maria Cristina; Hardacre, Christopher; Stepanenko, Vladimir; Albuquerque, Rodrigo Q.; Fern‚ndez, Gustavo
Data(s)

01/06/2016

Resumo

We report the self-assembly of a new family of hydrophobic,bis(pyridyl) PtII complexes featuring an extendedoligophenyleneethynylene-derived π-surface appended withsix long (dodecyloxy (2)) or short (methoxy (3)) side groups.Complex 2, containing dodecyloxy chains, forms fibrous assemblies with a slipped arrangement of the monomer units (dPt···Pt… =14 Å) in both nonpolar solvents and the solid state.Dispersion-corrected PM6 calculations suggest that this organizationis driven by cooperative π–π, C-H···Cl and π–Pt interactions, which is supported by EXAFS and 2D NMR spectroscopic analysis. In contrast, nearly parallel π-stacks (dPt···Pt… = 4.4 Å) stabilized by multiple π–π and C-H···Cl contact sare obtained in the crystalline state for 3 lacking longside chains, as shown by X-ray analysis and PM6 calculations.Our results reveal not only the key role of alkyl chain lengthin controlling self-assembly modes but also show the relevanceof Pt-bound chlorine ligands as new supramolecular synthons.

Identificador

http://pure.qub.ac.uk/portal/en/publications/control-over-the-selfassembly-modes-of-ptii-complexes-by-alkyl-chain-variation-from-slipped-to-parallel-stacks(3324b596-a135-4d06-8828-9519d7c32a05).html

http://dx.doi.org/10.1002/chem.201600176

Idioma(s)

eng

Direitos

info:eu-repo/semantics/closedAccess

Fonte

Allampally , N K , Mayoral , M J , Chansai , S , Lagunas , M C , Hardacre , C , Stepanenko , V , Albuquerque , R Q & Fern‚ndez , G 2016 , ' Control over the Self-Assembly Modes of PtII Complexes by Alkyl Chain Variation: From Slipped to Parallel π-Stacks ' Chemistry - A European Journal , vol 22 , no. 23 , pp. 7810-7816 . DOI: 10.1002/chem.201600176

Tipo

article