Asymmetric oxidation of sulfides
| Data(s) |
16/08/2016
16/08/2016
16/10/2012
16/08/2016
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| Resumo |
This review discusses synthesis of enantiopure sulfoxides through the asymmetric oxidation of prochiral sulfides. The use of metal complexes to promote asymmetric sulfoxidation is described in detail, with a particular emphasis on the synthesis of biologically active sulfoxides. The use of non-metal-based systems, such as oxaziridines, chiral hydroperoxides and peracids, as well as enzyme-catalyzed sulfoxidations is also examined. |
| Formato |
application/pdf |
| Identificador |
O'Mahony, G. E., Ford, A. and Maguire, A. R. (2013) 'Asymmetric oxidation of sulfides'. Journal of Sulfur Chemistry, 34(3), pp. 301-341. http://dx.doi.org/10.1080/17415993.2012.725247 34 3 301 341 1741-5993 1741-6000 http://hdl.handle.net/10468/2996 10.1080/17415993.2012.725247 Journal of Sulfur Chemistry |
| Idioma(s) |
en |
| Publicador |
Taylor and Francis |
| Direitos |
© 2013 Taylor and Francis Group, LLC. This is a Submitted Manuscript of an article published by Taylor & Francis in Journal of Sulfur Chemistry on 16 Oct 2012, available online: http://www.tandfonline.com/10.1080/17415993.2012.725247. |
| Palavras-Chave | #Sulfide oxidation #Sulfoxides #Asymmetric synthesis #Enantioselective synthesis #Metal-based catalysts #Alkyl aryl sulfides #Chiral schiff-bases #Helminthosporium species NRRL-4671 #Optically-active sulfoxides #Benzyl methyl sulfoxides #Aqueous hydrogen-peroxide #Tert-butyl hydroperoxide #Twin coronet porphyrins #Mandelic-acid complex #Bovine serum-albumin |
| Tipo |
Article (peer-reviewed) |
