The curtius rearrangement of acyl azides revisited - formation of cyanate (R-O-CN)
| Data(s) |
01/01/2005
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|---|---|
| Resumo |
The Curtius rearrangement is a synthesis of isocyanates (R-N=C=O) by thermal or photochemical rearrangement of acyl acides and/or acylnitrenes. The photochemical rearrangement of benzoyl azide is now shown for the first time to produce a small amount of phenyl cyanate (Ph-O-CN) together with phenyl isocyanate. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
Wiley |
| Palavras-Chave | #Chemistry, Organic #azides #reactive intermediates #nitrenes #isocyanates #cyanates #Alkyl Cyanates #Singlet #Photochemistry #Isomerization #Aroylnitrenes #States #Oxide #Chno #C1 #250303 Physical Organic Chemistry #780103 Chemical sciences |
| Tipo |
Journal Article |
