Nitrogen is a requirement for the photochemical induced 3-azabicyclo[3.3.1]nonane skeletal rearrangement!


Autoria(s): Williams, C. M.; Heim, R.; Bernhardt, P. V.
Data(s)

01/01/2005

Resumo

Specific 3-azabicyclo[3.3.1]nonane derivatives undergo skeletal cleavage when subjected to light or Lewis acidic conditions affording novel heteratricycles, which is in stark contrast to 3-oxabicyclo[3.3.1]nonanes. (c) 2005 Elsevier Ltd. All rights reserved.

Identificador

http://espace.library.uq.edu.au/view/UQ:76570

Idioma(s)

eng

Publicador

Pergamon-Elsevier

Palavras-Chave #Photochemistry #3-azabicyclo[3.3.1]nonane #Double Michael Reaction #Diterpene Alkaloids #Epi-modhephene #Methyllycaconitine #Acid #Ring #Conversion #Chemistry #Oxidation #Analogs #Chemistry, Organic #C1 #250301 Organic Chemical Synthesis #670403 Treatments (e.g. chemicals, antibiotics)
Tipo

Journal Article