Nitrogen is a requirement for the photochemical induced 3-azabicyclo[3.3.1]nonane skeletal rearrangement!
Data(s) |
01/01/2005
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Resumo |
Specific 3-azabicyclo[3.3.1]nonane derivatives undergo skeletal cleavage when subjected to light or Lewis acidic conditions affording novel heteratricycles, which is in stark contrast to 3-oxabicyclo[3.3.1]nonanes. (c) 2005 Elsevier Ltd. All rights reserved. |
Identificador | |
Idioma(s) |
eng |
Publicador |
Pergamon-Elsevier |
Palavras-Chave | #Photochemistry #3-azabicyclo[3.3.1]nonane #Double Michael Reaction #Diterpene Alkaloids #Epi-modhephene #Methyllycaconitine #Acid #Ring #Conversion #Chemistry #Oxidation #Analogs #Chemistry, Organic #C1 #250301 Organic Chemical Synthesis #670403 Treatments (e.g. chemicals, antibiotics) |
Tipo |
Journal Article |