Expedient construction of the vibsanin E core without the use of protecting groups
| Data(s) |
01/01/2005
|
|---|---|
| Resumo |
The tricyclic core of vibsanin E was constructed without the use of a protecting group in six steps. The El Gaied Baylis-Hillman variant was key to allowing the Bronsted acid induced tandem cyclization forming rings B and C in one operation. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
American Chemical Society |
| Palavras-Chave | #Chemistry, Organic #Beta-keto-esters #Baylis-hillman Reaction #Viburnum-odoratissimum Ker #Mediated Ring-expansion #Stereocontrolled Synthesis #Rate Acceleration #Group Migration #Cyclic Enones #Awabuki #Leaves #C1 #250301 Organic Chemical Synthesis #670403 Treatments (e.g. chemicals, antibiotics) |
| Tipo |
Journal Article |
