Geochemistry of labile organic matter in sediments and interstitial waters of ODP Sites 107-651 and 107-653
Cobertura |
MEDIAN LATITUDE: 40.217745 * MEDIAN LONGITUDE: 11.984152 * SOUTH-BOUND LATITUDE: 40.150500 * WEST-BOUND LONGITUDE: 11.449200 * NORTH-BOUND LATITUDE: 40.264300 * EAST-BOUND LONGITUDE: 12.756500 * DATE/TIME START: 1986-01-11T05:22:00 * DATE/TIME END: 1986-02-03T03:55:00 |
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Data(s) |
12/10/1990
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Resumo |
Sediment and interstitial water from Sites 651 and 653 (ODP Leg 107) were investigated by organic geochemical methods to characterize labile organic compound classes (amino compounds and carbohydrates) and to evaluate their progressive diagenetic and thermal degradation in deep-sea sediments. Downhole distribution of dissolved organic carbon (DOC) appears related to redox zones associated with bacterial activity and of diagenetic recrystallization of biogenic tests and not so much to organic matter concentrations in ambient sediments. DOC ranges from 250 to 8300 µmol/L (3-100.1 ppm). Amino acids contribute 10%-0.3% of DOC; carbohydrates range from 78 to 5 µmol/L. Rate of degradation of amino acids by thermal effects and/or bacterial activity at both sites (significantly different in sedimentation rates: average 41 cm/1000 yr in the top 300 m at Site 651, average 3.9 cm/1000 yr in the Pliocene/Quaternary sequence at Site 653 to 220 mbsf) is more dependent on exposure time rather than on the depth within the sediment column. Variability in neutral, acidic, and basic amino acid fractions of total amino acids (with a range of 1.1-0.02 µmol/g sediment; up to 2.5% of organic carbon) varies with carbonate content and by differences in thermal stability of amino acids. Distribution patterns of monosaccharides are interpreted to result from differences in organic matter sources, sedimentation rates, and the degree of organic matter decomposition prior to and subsequent to burial. Total particulate carbohydrates range from 1.82 to 0.21 µmol/g sediment and contribute about 8% to the sedimentary organic matter. Investigation of trace metals in the interstitial waters did not show any correlation of either DOC, amino compounds, or carbohydrates. |
Formato |
application/zip, 11 datasets |
Identificador |
https://doi.pangaea.de/10.1594/PANGAEA.746133 doi:10.1594/PANGAEA.746133 |
Idioma(s) |
en |
Publicador |
PANGAEA |
Direitos |
CC-BY: Creative Commons Attribution 3.0 Unported Access constraints: unrestricted |
Fonte |
Supplement to: Seifert, Richard; Emeis, Kay-Christian; Spitzy, Alejandro; Strahlendorff, K; Michaelis, Walter; Degens, Egon T (1990): Geochemistry of labile organic matter in sediments and interstitial water recovered from Sites 651 and 653, Leg 107 ODP in the Tyrrhenian Sea. In: Kastens, KA; Mascle, J; et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 107, 591-602, doi:10.2973/odp.proc.sr.107.143.1990 |
Palavras-Chave | #[SO4]2-; 107-651A; 107-653; 107-653A; 107-653B; AA; AA/Corg; AA/DOC; Ala; Alanine; Alkalinity, total; Amino acids; Amino acids/dissolved organic carbon ratio; Amino acids/organic carbon ratio; Amino sugars; Amino sugars/organic carbon ratio; Ara; Arabinose; Arg; Arginine; AS/Corg; Asp; Aspartic acid; AT; b-ala; beta-Alanine; Ca; Ca/Mg; CaCO3; Calcium; Calcium/Magnesium ratio; Calcium carbonate; Carbon, organic, dissolved; Carbon, organic, total; Chloride; Cl-; Comment; COMPCORE; Composite Core; Depth; DEPTH, sediment/rock; Description; DOC; DRILL; Drilling/drill rig; Event; Fe; Fru; Fructose; Fuc; Fucose; g-ABA; Gal; Gal/Fru; Galactosamine; Galactose; Galactose/Fucose ratio; GalN; gamma-Aminobutyric acid; GlcN; Glu; Glucosamine; Glucose; Glutamic acid; Gly; Glycine; His; Histidine; Ile; Iron; Isoleucine; Joides Resolution; K; Label; Leg107; Leu; Leucine; Lys; Lysine; Magnesium; Man; Manganese; Mannose; Met; Methionine; Mg; Mn; Ocean Drilling Program; ODP; ODP sample designation; Orn; Ornithine; pH; Phe; Phenylalanine; Potassium; Rha; Rhamnose; Rib; Ribose; Sal; Salinity; Sample code/label; Ser; Serine; Silicon dioxide; SiO2; Sr; Strontium; Sulphate; Thr; Threonine; Tirreno Sea; TOC; Tyr; Tyrosine; Val; Valine; Xyl; Xylose |
Tipo |
Dataset |