Magnetism and photophysics in supramolecular transition-metal compounds
| Data(s) |
1997
|
|---|---|
| Resumo |
Based on a synthetic strategy, extended anionic, homo and bimetallic oxalato-bridged transition-metal compounds with two (2D) and three-dimensional (3D) connectivities can be synthesized and crystallized. Thereby, the choice of the templating counterions will determine the crystal chemistry. Since the oxalato bridge is a mediator for both antiferro and ferromagnetic interactions between similar and dissimilar metal ions, long-range magnetic ordering will occur. Examples of the determination of magnetic structures in 2D and 3D compounds by means of elastic neutron scattering methods will be discussed. In addition, due to the possibility of the variation of different metal ions in varying oxidation states, interesting photophysical processes can be observed within the extended three-dimensional host/guest systems. |
| Formato |
application/pdf |
| Identificador |
http://boris.unibe.ch/82631/1/1-s2.0-S0379677997803992-main.pdf Decurtins, Silvio; Schmalle, H. W.; Pellaux, R.; Hauser, A.; von Arx, M. E.; Fischer, P. (1997). Magnetism and photophysics in supramolecular transition-metal compounds. Synthetic Metals, 85(1-3), pp. 1689-1694. Elsevier 10.1016/S0379-6779(97)80399-2 <http://dx.doi.org/10.1016/S0379-6779(97)80399-2> doi:10.7892/boris.82631 info:doi:10.1016/S0379-6779(97)80399-2 urn:issn:0379-6779 |
| Idioma(s) |
eng |
| Publicador |
Elsevier |
| Relação |
http://boris.unibe.ch/82631/ |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Decurtins, Silvio; Schmalle, H. W.; Pellaux, R.; Hauser, A.; von Arx, M. E.; Fischer, P. (1997). Magnetism and photophysics in supramolecular transition-metal compounds. Synthetic Metals, 85(1-3), pp. 1689-1694. Elsevier 10.1016/S0379-6779(97)80399-2 <http://dx.doi.org/10.1016/S0379-6779(97)80399-2> |
| Palavras-Chave | #570 Life sciences; biology #540 Chemistry |
| Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion PeerReviewed |
