Isobaric vapor–liquid–liquid–solid equilibrium of the water + NaCl + 1-butanol system at 101.3 kPa
Contribuinte(s) |
Universidad de Alicante. Departamento de Ingeniería Química Universidad de Alicante. Instituto Universitario de Ingeniería de los Procesos Químicos Equilibrio entre Fases |
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Data(s) |
20/06/2016
20/06/2016
01/09/2016
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Resumo |
A mixture of water + NaCl + 1-butanol at 101.3 kPa is studied in order to determine the influence of salt on its experimental vapor–liquid–liquid–solid equilibrium. A detailed analysis of the evolution with temperature of the different equilibrium regions is carried out. The study is conducted at a constant pressure of 101.3 kPa in a recirculating still that has been modified by our research group. The changes in the 1-butanol/water composition ratio in the vapor phase that are provoked by the salt are studied as a function of equilibrium region. In addition, the mutual solubility of 1-butanol and water is assessed in the liquid–liquid and solid–liquid regions. The authors thank the DGICYT of Spain for the financial support of project CTQ2009-13770 and CTQ2014-59496. |
Identificador |
Journal of Chemical Thermodynamics. 2016, 100: 53-59. doi:10.1016/j.jct.2016.04.013 0021-9614 (Print) 1096-3626 (Online) http://hdl.handle.net/10045/56046 10.1016/j.jct.2016.04.013 |
Idioma(s) |
eng |
Publicador |
Elsevier |
Relação |
http://dx.doi.org/10.1016/j.jct.2016.04.013 |
Direitos |
© 2016 Elsevier Ltd. info:eu-repo/semantics/embargoedAccess |
Palavras-Chave | #Water #1-Butanol #NaCl #Isobaric #Vapor–liquid–liquid–solid #Equilibrium data #Ingeniería Química |
Tipo |
info:eu-repo/semantics/article |