Interaction of water with methanesulfonic acid on Pt single crystal electrodes


Autoria(s): Sandoval, Andrea P.; Suárez-Herrera, Marco F.; Climent, Victor; Feliu, Juan M.
Contribuinte(s)

Universidad de Alicante. Departamento de Química Física

Universidad de Alicante. Instituto Universitario de Electroquímica

Electroquímica de Superficies

Data(s)

03/12/2014

03/12/2014

01/01/2015

Resumo

The electrochemical behavior of methanesulfonic acid on platinum single crystal electrode surfaces is investigated by cyclic voltammetry and infrared spectroscopy measurements. The results are compared with the voltammetric profiles of perchloric and trifluoromethanesulfonic acids. The differences are interpreted in terms of the effect of the anion on the structure of water. No adsorbed species are detected by infrared spectroscopy.

APS acknowledges the scholarship “Estudiantes sobresalientes de posgrado” at the UNC and COLCIENCIAS National Doctoral Scholarship (567). MFS acknowledges the support of UNC (Research Project 19030). JMFwould like to thankGeneralitat Valenciana (Feder) through project PROMETEOII/2014/013.

Identificador

Electrochemistry Communications. 2015, 50: 47-50. doi:10.1016/j.elecom.2014.11.007

1388-2481 (Print)

1873-1902 (Online)

http://hdl.handle.net/10045/43030

10.1016/j.elecom.2014.11.007

Idioma(s)

eng

Publicador

Elsevier

Relação

http://dx.doi.org/10.1016/j.elecom.2014.11.007

Direitos

info:eu-repo/semantics/openAccess

Palavras-Chave #Methanesulfonic acid #Platinum single crystal electrodes #Cyclic voltammetry #Anion adsorption #Química Física
Tipo

info:eu-repo/semantics/article