Interaction of water with methanesulfonic acid on Pt single crystal electrodes
Contribuinte(s) |
Universidad de Alicante. Departamento de Química Física Universidad de Alicante. Instituto Universitario de Electroquímica Electroquímica de Superficies |
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Data(s) |
03/12/2014
03/12/2014
01/01/2015
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Resumo |
The electrochemical behavior of methanesulfonic acid on platinum single crystal electrode surfaces is investigated by cyclic voltammetry and infrared spectroscopy measurements. The results are compared with the voltammetric profiles of perchloric and trifluoromethanesulfonic acids. The differences are interpreted in terms of the effect of the anion on the structure of water. No adsorbed species are detected by infrared spectroscopy. APS acknowledges the scholarship “Estudiantes sobresalientes de posgrado” at the UNC and COLCIENCIAS National Doctoral Scholarship (567). MFS acknowledges the support of UNC (Research Project 19030). JMFwould like to thankGeneralitat Valenciana (Feder) through project PROMETEOII/2014/013. |
Identificador |
Electrochemistry Communications. 2015, 50: 47-50. doi:10.1016/j.elecom.2014.11.007 1388-2481 (Print) 1873-1902 (Online) http://hdl.handle.net/10045/43030 10.1016/j.elecom.2014.11.007 |
Idioma(s) |
eng |
Publicador |
Elsevier |
Relação |
http://dx.doi.org/10.1016/j.elecom.2014.11.007 |
Direitos |
info:eu-repo/semantics/openAccess |
Palavras-Chave | #Methanesulfonic acid #Platinum single crystal electrodes #Cyclic voltammetry #Anion adsorption #Química Física |
Tipo |
info:eu-repo/semantics/article |