First aromatic ring acetamidation by anodic oxidation
Contribuinte(s) |
Universidad de Alicante. Departamento de Química Orgánica Universidad de Alicante. Instituto Universitario de Síntesis Orgánica Nuevos Materiales y Catalizadores (MATCAT) |
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Data(s) |
01/10/2014
01/10/2014
01/11/2014
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Resumo |
Anodic oxidation of 1-(trifluoromethyl)benzene in dry acetonitrile/Bu4NBF4 under constant potential conditions led to 2-(trifluoromethyl) acetanilide in 86% yield. Other experimental conditions, as the use of constant current or the change in the supporting electrolyte were considered. This work was supported by the Spanish Ministry of Science and Education through B. Batanero I3 program the financial support. |
Identificador |
Electrochemistry Communications. 2014, 48: 115-117. doi:10.1016/j.elecom.2014.08.028 1388-2481 (Print) 1873-1902 (Online) http://hdl.handle.net/10045/40804 10.1016/j.elecom.2014.08.028 |
Idioma(s) |
eng |
Publicador |
Elsevier |
Relação |
http://dx.doi.org/10.1016/j.elecom.2014.08.028 |
Direitos |
info:eu-repo/semantics/openAccess |
Palavras-Chave | #Acetanilides #Anode #1-(Trifluoromethyl)benzene #Acetonitrile/Bu4NBF4 #Potentiostatic conditions #Química Orgánica |
Tipo |
info:eu-repo/semantics/article |