First aromatic ring acetamidation by anodic oxidation


Autoria(s): Barba, Fructuoso; Barba, Isidoro; Batanero, Belén
Contribuinte(s)

Universidad de Alicante. Departamento de Química Orgánica

Universidad de Alicante. Instituto Universitario de Síntesis Orgánica

Nuevos Materiales y Catalizadores (MATCAT)

Data(s)

01/10/2014

01/10/2014

01/11/2014

Resumo

Anodic oxidation of 1-(trifluoromethyl)benzene in dry acetonitrile/Bu4NBF4 under constant potential conditions led to 2-(trifluoromethyl) acetanilide in 86% yield. Other experimental conditions, as the use of constant current or the change in the supporting electrolyte were considered.

This work was supported by the Spanish Ministry of Science and Education through B. Batanero I3 program the financial support.

Identificador

Electrochemistry Communications. 2014, 48: 115-117. doi:10.1016/j.elecom.2014.08.028

1388-2481 (Print)

1873-1902 (Online)

http://hdl.handle.net/10045/40804

10.1016/j.elecom.2014.08.028

Idioma(s)

eng

Publicador

Elsevier

Relação

http://dx.doi.org/10.1016/j.elecom.2014.08.028

Direitos

info:eu-repo/semantics/openAccess

Palavras-Chave #Acetanilides #Anode #1-(Trifluoromethyl)benzene #Acetonitrile/Bu4NBF4 #Potentiostatic conditions #Química Orgánica
Tipo

info:eu-repo/semantics/article