Recent Advances in the Catalytic Enantioselective Reformatsky Reaction


Autoria(s): Fernández Ibáñez, María Ángeles; Maciá, Beatriz; Alonso, Diego A.; Pastor, Isidro M.
Contribuinte(s)

Universidad de Alicante. Departamento de Química Orgánica

Universidad de Alicante. Instituto Universitario de Síntesis Orgánica

Catálisis Estereoselectiva en Síntesis Orgánica (CESO)

Nuevos Materiales y Catalizadores (MATCAT)

Data(s)

19/06/2014

19/06/2014

01/11/2013

Resumo

This paper reviews the present state of the catalytic enantioselective Reformatsky reaction. Advancements in asymmetric versions of this reaction have recently led to a considerable extension of its scope and applicability, principally due to the use of highly active chiral ligands and very specific reaction conditions.

M. A. F. I. is grateful for financial support from the Ministerio de Economía y Competitividad (MINECO) (CTQ 2012-35790) and the Consejería de Educación de la Comunidad de Madrid (programme AVANCAT, S2009/PPQ-1634). B. M. thanks the European Commission for a Marie Curie Integration Grant (FP7-PEOPLE-2012-CIG). I. M. P. and D. A. A. are grateful for financial support from the Spanish Ministerio de Ciencia e Innovación (MICINN) (project numbers CTQ2011-24165 and CTQ2010-20387, respectively) and from the University of Alicante.

Identificador

European Journal of Organic Chemistry. 2013, 2013(31): 7028-7034. doi:10.1002/ejoc.201300571

1434-193X (Print)

1099-0690 (Online)

http://hdl.handle.net/10045/38215

10.1002/ejoc.201300571

Idioma(s)

eng

Publicador

Wiley-VCH Verlag GmbH & Co. KGaA

Relação

http://dx.doi.org/10.1002/ejoc.201300571

Direitos

© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the pre-peer reviewed version of the following article: M. Ángeles Fernández-Ibáñez, Beatriz Maciá, Diego A. Alonso, Isidro M. Pastor, Recent Advances in the Catalytic Enantioselective Reformatsky Reaction, European Journal of Organic Chemistry. 2013, 2013(31): 7028-7034, which has been published in final form at http://dx.doi.org/10.1002/ejoc.201300571

info:eu-repo/semantics/openAccess

Palavras-Chave #Enantioselectivity #Asymmetric catalysis #Organozinc reagent #Reformatsky reaction #Chiral ligands #Zinc #Química Orgánica
Tipo

info:eu-repo/semantics/article