Desilication of TS-1 zeolite for the oxidation of bulky molecules


Autoria(s): Silvestre Albero, Ana; Grau Atienza, Aida; Serrano, Elena; Garcia-Martinez, Javier; Silvestre-Albero, Joaquín
Contribuinte(s)

Universidad de Alicante. Departamento de Química Inorgánica

Universidad de Alicante. Instituto Universitario de Materiales

Materiales Avanzados

Laboratorio de Nanotecnología Molecular (NANOMOL)

Data(s)

30/05/2014

30/05/2014

10/01/2014

Resumo

A series of modified TS-1 samples have been produced by desilication of the original TS-1 (4 wt.% Ti) using a chemical treatment with NaOH. Desilicated TS-1 zeolites exhibit a large BET surface area together with a well-developed mesoporosity. The hierarchical catalysts from desilication of TS-1 zeolite show a good catalytic activity for the oxidation of small molecules and a significantly higher activity for the oxidation of bulky molecules.

Identificador

Catalysis Communications. 2014, 44: 35-39. doi:10.1016/j.catcom.2013.08.004

1566-7367 (Print)

1873-3905 (Online)

http://hdl.handle.net/10045/37737

10.1016/j.catcom.2013.08.004

Idioma(s)

eng

Publicador

Elsevier

Relação

http://dx.doi.org/10.1016/j.catcom.2013.08.004

Direitos

info:eu-repo/semantics/openAccess

Palavras-Chave #Desilication #Hierarchical catalysts #TS-1 #Epoxidation reactions #Química Inorgánica
Tipo

info:eu-repo/semantics/article