Heterocyclic carbene–metal-catalyzed Csp2–Csp2 and Csp–Csp2 couplings using nonmetallic substrates
| Contribuinte(s) |
Universidad de Alicante. Departamento de Química Orgánica Síntesis Asimétrica (SINTAS) Nuevos Materiales y Catalizadores (MATCAT) |
|---|---|
| Data(s) |
04/12/2013
04/12/2013
02/02/2013
|
| Resumo |
The use of carbene ligands for transition-metal complexes has been developed in the last decades, being of special interest those carbenes derived from a nitrogen-containing heterocyclic system. An interesting variety of carbene-metal complexes has been tested in the Mizoroki-Heck reaction. In comparison, few examples can be found for the Matsuda-Heck version of this coupling reaction. Additionally, the Sonogashira coupling has been also catalyzed with different carbene-metal catalysts. Financial support from the Ministerio de Ciencia e Innovación (MICINN) of Spain (Project Nos. CTQ2007-65218, CTQ2011-24165, Consolider Ingenio 2010 CSD2007-00006), and the Generalitat Valencia (PROMETEO/2009/0349 and FEDER), and the University of Alicante is acknowledged. |
| Identificador |
Chemistry Letters. 2013, 42(2): 94-108. doi:10.1246/cl.2013.94 0366-7022 (Print) 1348-0715 (Online) http://hdl.handle.net/10045/34359 10.1246/cl.2013.94 |
| Idioma(s) |
eng |
| Publicador |
Chemical Society of Japan |
| Relação |
http://dx.doi.org/10.1246/cl.2013.94 |
| Direitos |
Copyright © 2013 The Chemical Society of Japan info:eu-repo/semantics/openAccess |
| Palavras-Chave | #Carbene–metal catalysts #Mizoroki–Heck reaction #Matsuda–Heck reaction #Sonogashira reaction #Química Orgánica |
| Tipo |
info:eu-repo/semantics/article |
