Asymmetric aldol reaction with BINAM-sulfonyl polymeric organocatalyst
| Contribuinte(s) |
Universidad de Alicante. Departamento de Química Orgánica Derivados de Aminoácidos y Péptidos en Síntesis Orgánica Procesos Catalíticos en Síntesis Orgánica |
|---|---|
| Data(s) |
16/01/2013
16/01/2013
17/12/2012
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| Resumo |
The BINAM-sulfonyl polymeric organocatalysts was prepared by the AIBN-promoted copolymerization of BINAM-derived sulfonamide, styrene and divinylbenzebe. The polymer catalyzed the asymmetric aldol reaction of aliphatic ketones with aromatic aldehydes to give the aldol products in up to 83% yield and with up to 95% ee. The catalysts could be recovered upt to 6 times with only a slight decrease on its activity. |
| Identificador |
BAÑÓN-CABALLERO, A.; GUILLENA, G.; NÁJERA, C. “Asymmetric aldol reaction with BINAM-sulfonyl polymeric organocatalyst”. Synfacts. Vol. 9, No. 1 (2013). ISSN 1861-1958, p. 114 1861-1958 (Print) 1861-194X (Online) http://hdl.handle.net/10045/25968 10.1055/s-0032-1317913 A6604726 |
| Idioma(s) |
eng |
| Publicador |
Georg Thieme Verlag |
| Relação |
http://dx.doi.org/10.1055/s-0032-1317913 |
| Direitos |
© Georg Thieme Verlag Stuttgart · New York info:eu-repo/semantics/restrictedAccess |
| Palavras-Chave | #Asymmmetic #Aldol #Polymer #Organocatalyst #Química Orgánica |
| Tipo |
info:eu-repo/semantics/review |
