Stabilisation of low softening point petroleum pitch fibres by iodine treatment


Autoria(s): Vilaplana Ortego, Eduardo; Alcañiz-Monge, Juan; Cazorla-Amorós, Diego; Linares-Solano, Angel
Contribuinte(s)

Universidad de Alicante. Departamento de Química Inorgánica

Materiales Carbonosos y Medio Ambiente

Data(s)

19/01/2012

19/01/2012

2006

01/03/2007

Resumo

A method using iodine has been developed for the stabilisation of low softening point (SP) pitch fibres that avoids air stabilisation in the production of carbon fibres (CF). The interaction between iodine and petroleum pitches has been studied by following the changes in the hydrogen content, aromatic or aliphatic, during the heat treatment of iodine-treated pitch fibres. Two low SP petroleum pitches were used and the iodine-treated pitch fibres were analysed by TGA, DSC, DRIFT, XPS and SEM. The results confirm that using this novel method pitches with low SP can be used to prepare CF with two advantages, compared with conventional methods. The stabilisation time is considerably reduced and treatments to increase the SP, usually required when low SP pitches are used to prepare CF, can be avoided.

Spanish Government (project PPQ2003-03884).

Identificador

VILAPLANA-ORTEGO, E., et al. "Stabilisation of low softening point petroleum pitch fibres by iodine treatment". Fuel Processing Technology. Vol. 88, Issue 3 (March 2007). ISSN 0378-3820, pp. 265-272

0378-3820 (Print)

1873-7188 (Online)

http://hdl.handle.net/10045/20438

10.1016/j.fuproc.2006.10.005

Idioma(s)

eng

Publicador

Elsevier

Relação

http://dx.doi.org/10.1016/j.fuproc.2006.10.005

Direitos

info:eu-repo/semantics/restrictedAccess

Palavras-Chave #Petroleum pitch #Carbon fibres #Stabilisation #Ciencia de los Materiales e Ingeniería Metalúrgica #Química Inorgánica
Tipo

info:eu-repo/semantics/article