Pulse-shaping assisted multidimensional coherent electronic spectroscopy
Data(s) |
2015
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Resumo |
Understanding nuclear and electronic dynamics of molecular systems has advanced considerably by probing their nonlinear responses with a suitable sequence of pulses. Moreover, the ability to control crucial parameters of the excitation pulses, such as duration, sequence, frequency, polarization, slowly varying envelope, or carrier phase, has led to a variety of advanced time-resolved spectroscopic methodologies. Recently, two-dimensional electronic spectroscopy with ultrashort pulses has become a more and more popular tool since it allows to obtain information on energy and coherence transfer phenomena, line broadening mechanisms, or the presence of quantum coherences in molecular complexes. Here, we present a high fidelity two-dimensional electronic spectroscopy setup designed for molecular systems in solution. It incorporates the versatility of pulse-shaping methods to achieve full control on the amplitude and phase of the individual exciting and probing pulses. Selective and precise amplitude- and phase-modulation is shown and applied to investigate electronic dynamics in several reference molecular systems. |
Formato |
application/pdf |
Identificador |
http://boris.unibe.ch/74998/1/1.4921793.pdf Rodriguez Consuegra, Yuseff; Frei, Franziska; Cannizzo, Andrea; Feurer, Thomas (2015). Pulse-shaping assisted multidimensional coherent electronic spectroscopy. The Journal of Chemical Physics, 142(21), p. 212451. American Institute of Physics 10.1063/1.4921793 <http://dx.doi.org/10.1063/1.4921793> doi:10.7892/boris.74998 info:doi:10.1063/1.4921793 urn:issn:0021-9606 |
Idioma(s) |
eng |
Publicador |
American Institute of Physics |
Relação |
http://boris.unibe.ch/74998/ |
Direitos |
info:eu-repo/semantics/openAccess |
Fonte |
Rodriguez Consuegra, Yuseff; Frei, Franziska; Cannizzo, Andrea; Feurer, Thomas (2015). Pulse-shaping assisted multidimensional coherent electronic spectroscopy. The Journal of Chemical Physics, 142(21), p. 212451. American Institute of Physics 10.1063/1.4921793 <http://dx.doi.org/10.1063/1.4921793> |
Palavras-Chave | #500 Science #530 Physics #620 Engineering |
Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion PeerReviewed |