Chemistry of pyrrocorphins: methylative opening of the macrocycle between rings A and D, a side reaction in the peripheral C-methylation of a 20-methyl-pyrrocorphinate
| Data(s) |
1984
|
|---|---|
| Resumo |
One of the minor products from the previously described peripheral -methylation of a magnesium()-20-methyl--pyrrocorphinate is a C-19-methylated 19,20-seco-corphinoid derivative which, on complexation with nickel() acetate, recyclizes to a nickel()-tetradehydro-corrinate. |
| Formato |
application/pdf |
| Identificador |
http://boris.unibe.ch/68882/1/c39840000583.pdf Leumann, Christian; Eschenmoser, Albert (1984). Chemistry of pyrrocorphins: methylative opening of the macrocycle between rings A and D, a side reaction in the peripheral C-methylation of a 20-methyl-pyrrocorphinate. Journal of the Chemical Society, Chemical Communications(9), p. 583. Royal Society of Chemistry 10.1039/c39840000583 <http://dx.doi.org/10.1039/c39840000583> doi:10.7892/boris.68882 info:doi:10.1039/c39840000583 urn:issn:0022-4936 |
| Idioma(s) |
eng |
| Publicador |
Royal Society of Chemistry |
| Relação |
http://boris.unibe.ch/68882/ |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Leumann, Christian; Eschenmoser, Albert (1984). Chemistry of pyrrocorphins: methylative opening of the macrocycle between rings A and D, a side reaction in the peripheral C-methylation of a 20-methyl-pyrrocorphinate. Journal of the Chemical Society, Chemical Communications(9), p. 583. Royal Society of Chemistry 10.1039/c39840000583 <http://dx.doi.org/10.1039/c39840000583> |
| Palavras-Chave | #570 Life sciences; biology #540 Chemistry |
| Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion PeerReviewed |
