Novel unsymmetrically functionalized BEDT–TTF derivatives: synthesis, crystal structure and electrochemical characterization
| Data(s) |
2003
|
|---|---|
| Resumo |
Novel functionalized bis(ethylenedithio)tetrathiafulvalene (BEDT–TTF) derivatives 4 and 5 have been synthesized in good yields from cyano precursor via a cross-coupling reaction. Their redox potentials have been studied by cyclic voltammetry in a dichloromethane solution; this indicated that they are slightly weaker electron donors than BEDT–TTF. Compound 4 has been studied by X–ray crystallography; this revealed that, in the crystal, the molecules were held together by some unconventional C–H···N and C–H···S hydrogen bonds. |
| Formato |
application/pdf |
| Identificador |
http://boris.unibe.ch/68531/1/1-s2.0-S1631074803001188-main.pdf Liu, Shi-Xia; Dolder, Stefan; Rusanov, Eduard B; Stoeckli-Evans, Helen; Decurtins, Silvio (2003). Novel unsymmetrically functionalized BEDT–TTF derivatives: synthesis, crystal structure and electrochemical characterization. Comptes rendus - chimie, 6(7), pp. 657-662. Elsevier 10.1016/S1631-0748(03)00118-8 <http://dx.doi.org/10.1016/S1631-0748(03)00118-8> doi:10.7892/boris.68531 info:doi:10.1016/S1631-0748(03)00118-8 urn:issn:1631-0748 |
| Idioma(s) |
eng |
| Publicador |
Elsevier |
| Relação |
http://boris.unibe.ch/68531/ |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Liu, Shi-Xia; Dolder, Stefan; Rusanov, Eduard B; Stoeckli-Evans, Helen; Decurtins, Silvio (2003). Novel unsymmetrically functionalized BEDT–TTF derivatives: synthesis, crystal structure and electrochemical characterization. Comptes rendus - chimie, 6(7), pp. 657-662. Elsevier 10.1016/S1631-0748(03)00118-8 <http://dx.doi.org/10.1016/S1631-0748(03)00118-8> |
| Palavras-Chave | #570 Life sciences; biology #540 Chemistry |
| Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion PeerReviewed |
