Decoupling surface reconstruction and perchlorate adsorption on Au(111)


Autoria(s): Zhumaev, Ulmas; Pobelov, Ilya; Rudnev, Alexander; Kuzume, Akiyoshi; Wandlowski, Thomas
Data(s)

24/04/2014

Resumo

On Au(111) electrodes, the investigation of ClO4− adsorption is hampered by a simultaneous surface reconstruction. We demonstrate that these two processes can be decoupled in cyclic voltammograms by a proper choice of the scan rate and of the initial potential. Our approach allowed the establishment of a relation between potentials of zero charge for the reconstructed and unreconstructed Au(111) surfaces.

Formato

application/pdf

Identificador

http://boris.unibe.ch/65948/1/1-s2.0-S1388248114001155-main.pdf

Zhumaev, Ulmas; Pobelov, Ilya; Rudnev, Alexander; Kuzume, Akiyoshi; Wandlowski, Thomas (2014). Decoupling surface reconstruction and perchlorate adsorption on Au(111). Electrochemistry communications, 44, pp. 31-33. Elsevier 10.1016/j.elecom.2014.04.009 <http://dx.doi.org/10.1016/j.elecom.2014.04.009>

doi:10.7892/boris.65948

info:doi:10.1016/j.elecom.2014.04.009

urn:issn:1388-2481

Idioma(s)

eng

Publicador

Elsevier

Relação

http://boris.unibe.ch/65948/

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Zhumaev, Ulmas; Pobelov, Ilya; Rudnev, Alexander; Kuzume, Akiyoshi; Wandlowski, Thomas (2014). Decoupling surface reconstruction and perchlorate adsorption on Au(111). Electrochemistry communications, 44, pp. 31-33. Elsevier 10.1016/j.elecom.2014.04.009 <http://dx.doi.org/10.1016/j.elecom.2014.04.009>

Palavras-Chave #570 Life sciences; biology #540 Chemistry #500 Science
Tipo

info:eu-repo/semantics/article

info:eu-repo/semantics/publishedVersion

PeerReviewed