Highly-effective gating of single-molecule junctions: an electrochemical approach
| Data(s) |
04/11/2014
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|---|---|
| Resumo |
We report an electrochemical gating approach with [similar]100% efficiency to tune the conductance of single-molecule 4,4′-bipyridine junctions using scanning-tunnelling-microscopy break junction technique. Density functional theory calculation suggests that electrochemical gating aligns molecular frontier orbitals relative to the electrode Fermi-level, switching the molecule from an off resonance state to “partial” resonance. |
| Formato |
application/pdf |
| Identificador |
http://boris.unibe.ch/65926/1/c4cc06519k.pdf Baghernejad, Masoud; Manrique, David Zsolt; Li, Chen; Pope, Thomas; Zhumaev, Ulmas; Pobelov, Ilya; Moreno, Pavel; Kaliginedi, Veera Bhadra Rao; Huang, Cancan; Hong, Wenjing; Lambert, Colin; Wandlowski, Thomas (2014). Highly-effective gating of single-molecule junctions: an electrochemical approach. Chemical communications, 50(100), pp. 15975-15978. Royal Society of Chemistry 10.1039/C4CC06519K <http://dx.doi.org/10.1039/C4CC06519K> doi:10.7892/boris.65926 info:doi:10.1039/C4CC06519K urn:issn:1359-7345 |
| Idioma(s) |
eng |
| Publicador |
Royal Society of Chemistry |
| Relação |
http://boris.unibe.ch/65926/ |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Baghernejad, Masoud; Manrique, David Zsolt; Li, Chen; Pope, Thomas; Zhumaev, Ulmas; Pobelov, Ilya; Moreno, Pavel; Kaliginedi, Veera Bhadra Rao; Huang, Cancan; Hong, Wenjing; Lambert, Colin; Wandlowski, Thomas (2014). Highly-effective gating of single-molecule junctions: an electrochemical approach. Chemical communications, 50(100), pp. 15975-15978. Royal Society of Chemistry 10.1039/C4CC06519K <http://dx.doi.org/10.1039/C4CC06519K> |
| Palavras-Chave | #570 Life sciences; biology #540 Chemistry #500 Science #520 Astronomy |
| Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion PeerReviewed |
