Stabilizing Lead Cathodes with Diammonium Salt Additives in the Deoxygenation of Aromatic Amides
Data(s) |
11/06/2014
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Resumo |
Lead is efficiently protected against cathodic corrosion by the addition of diammonium salts in the electrolyte. The cationic coating of the cathode allows the efficient electroreduction of benzamides to benzylamines. The electrochemical deoxygenation of the amide is achieved without the use of oxophilic agents or sacrificial anodes. The surface of the lead cathode stays smooth and the cathode can be reused for multiple runs, providing <2.5 ppm of the crude product. Cyclic voltammetry studies reveal a shift in the onset potential of the hydrogen evolution reaction by −157 mV. |
Formato |
application/pdf |
Identificador |
http://boris.unibe.ch/65767/1/1018_ftp.pdf Edinger, Carolin; Grimaudo, Valentine; Broekmann, Peter; Waldvogel, Siegfried R. (2014). Stabilizing Lead Cathodes with Diammonium Salt Additives in the Deoxygenation of Aromatic Amides. ChemElectroChem, 1(6), pp. 1018-1022. Wiley 10.1002/celc.201402050 <http://dx.doi.org/10.1002/celc.201402050> doi:10.7892/boris.65767 info:doi:10.1002/celc.201402050 urn:issn:2196-0216 |
Idioma(s) |
eng |
Publicador |
Wiley |
Relação |
http://boris.unibe.ch/65767/ |
Direitos |
info:eu-repo/semantics/restrictedAccess |
Fonte |
Edinger, Carolin; Grimaudo, Valentine; Broekmann, Peter; Waldvogel, Siegfried R. (2014). Stabilizing Lead Cathodes with Diammonium Salt Additives in the Deoxygenation of Aromatic Amides. ChemElectroChem, 1(6), pp. 1018-1022. Wiley 10.1002/celc.201402050 <http://dx.doi.org/10.1002/celc.201402050> |
Palavras-Chave | #570 Life sciences; biology #540 Chemistry #500 Science |
Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion PeerReviewed |