New magnetic frameworks of [(CuF 2 (H 2 O) 2 ) x (pyz)]
| Data(s) |
2014
|
|---|---|
| Resumo |
Pressure-driven orbital reordering in the quantum magnet [CuF2(H2O)2- (pyz)], (pyz = pyrazine), dramatically affects its magnetic exchange interactions. The crystal chemistry of this system is enriched with a new phase above 3 GPa, surprisingly concomitant with other polymorphs. Moreover, we discovered an unprecedented compound with a different stoichiometry, [(CuF2(H2O)2)2(pyz)], featuring magnetic bi-layers. |
| Formato |
application/pdf |
| Identificador |
http://boris.unibe.ch/59676/1/c4cc06696k.pdf Lanza, Arianna; Fiolka, Christoph; Fisch, Martin; Casati, N.; Skoulatos, M.; Rüegg, C.; Krämer, Karl; Macchi, Piero (2014). New magnetic frameworks of [(CuF 2 (H 2 O) 2 ) x (pyz)]. Chemical communications, 50(93), pp. 14504-14507. Royal Society of Chemistry 10.1039/C4CC06696K <http://dx.doi.org/10.1039/C4CC06696K> doi:10.7892/boris.59676 info:doi:10.1039/C4CC06696K urn:issn:1359-7345 |
| Idioma(s) |
eng |
| Publicador |
Royal Society of Chemistry |
| Relação |
http://boris.unibe.ch/59676/ |
| Direitos |
info:eu-repo/semantics/openAccess |
| Fonte |
Lanza, Arianna; Fiolka, Christoph; Fisch, Martin; Casati, N.; Skoulatos, M.; Rüegg, C.; Krämer, Karl; Macchi, Piero (2014). New magnetic frameworks of [(CuF 2 (H 2 O) 2 ) x (pyz)]. Chemical communications, 50(93), pp. 14504-14507. Royal Society of Chemistry 10.1039/C4CC06696K <http://dx.doi.org/10.1039/C4CC06696K> |
| Palavras-Chave | #540 Chemistry |
| Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion PeerReviewed |
