Radical chain reactions involving 9-alkyl-9-borafluorenes
| Data(s) |
2014
|
|---|---|
| Resumo |
The preparation of 9-alkyl-9-borafluorenes and their use as radical precursors in chain reactions were investigated. These organoboranes were found to be excellent precursors of primary and secondary alkyl radicals. Reactions were readily initiated by traces of oxygen and efficient processes involving sulfonyl-based radical traps were discovered. Due to the very high reactivity of the intermediate 9-H and 9-alkyl-9-borafluorenes, problems of reproducibility were identified. |
| Formato |
application/pdf |
| Identificador |
http://boris.unibe.ch/55022/1/5550190.p008.548.pdf Gorokhovik, Ioulia; Rieder, Samuel; Povie, Guillaume; Renaud, Philippe (2014). Radical chain reactions involving 9-alkyl-9-borafluorenes. Arkivoc, 2014(3), pp. 274-286. Michigan Publishing 10.3998/ark.5550190.p008.548 <http://dx.doi.org/10.3998/ark.5550190.p008.548> doi:10.7892/boris.55022 info:doi:10.3998/ark.5550190.p008.548 urn:issn:1551-7012 |
| Idioma(s) |
eng |
| Publicador |
Michigan Publishing |
| Relação |
http://boris.unibe.ch/55022/ |
| Direitos |
info:eu-repo/semantics/openAccess |
| Fonte |
Gorokhovik, Ioulia; Rieder, Samuel; Povie, Guillaume; Renaud, Philippe (2014). Radical chain reactions involving 9-alkyl-9-borafluorenes. Arkivoc, 2014(3), pp. 274-286. Michigan Publishing 10.3998/ark.5550190.p008.548 <http://dx.doi.org/10.3998/ark.5550190.p008.548> |
| Palavras-Chave | #570 Life sciences; biology #540 Chemistry |
| Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion PeerReviewed |
