Electronic tuning effects via cyano substitution of a fused tetrathiafulvalene–benzothiadiazole dyad for ambipolar transport properties


Autoria(s): Amacher, Anneliese; Luo, Hewei; Liu, Zitong; Bircher, Martin; Cascella, Michele; Hauser, Jürg; Decurtins, Silvio; Zhang, Deqing; Liu, Shi-Xia
Data(s)

2014

Resumo

Electronic tuning effects of substituents at the 4- and 8-positions of benzothiadiazole (BTD) within the fused tetrathiafulvalene–BTD donor–acceptor dyad have been studied. The electron acceptor strength of BTD is greatly increased by replacing Br with CN groups, extending the optical absorption of the small dyad into the near-IR region and importantly, the charge transport can be switched from p-type to ambipolar behaviour.

Formato

application/pdf

Identificador

http://boris.unibe.ch/49523/1/c3ra46784h.pdf

Amacher, Anneliese; Luo, Hewei; Liu, Zitong; Bircher, Martin; Cascella, Michele; Hauser, Jürg; Decurtins, Silvio; Zhang, Deqing; Liu, Shi-Xia (2014). Electronic tuning effects via cyano substitution of a fused tetrathiafulvalene–benzothiadiazole dyad for ambipolar transport properties. RSC advances, 4(6), pp. 2873-2878. Royal Society of Chemistry 10.1039/c3ra46784h <http://dx.doi.org/10.1039/c3ra46784h>

doi:10.7892/boris.49523

info:doi:10.1039/c3ra46784h

urn:issn:2046-2069

Idioma(s)

eng

Publicador

Royal Society of Chemistry

Relação

http://boris.unibe.ch/49523/

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Amacher, Anneliese; Luo, Hewei; Liu, Zitong; Bircher, Martin; Cascella, Michele; Hauser, Jürg; Decurtins, Silvio; Zhang, Deqing; Liu, Shi-Xia (2014). Electronic tuning effects via cyano substitution of a fused tetrathiafulvalene–benzothiadiazole dyad for ambipolar transport properties. RSC advances, 4(6), pp. 2873-2878. Royal Society of Chemistry 10.1039/c3ra46784h <http://dx.doi.org/10.1039/c3ra46784h>

Palavras-Chave #570 Life sciences; biology #540 Chemistry #500 Science
Tipo

info:eu-repo/semantics/article

info:eu-repo/semantics/publishedVersion

PeerReviewed