Charge Transport in Photoswitchable Dimethyldihydropyrene-Type Single-Molecule Junctions
| Data(s) |
11/04/2013
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|---|---|
| Resumo |
The conductance properties of a photoswitchable dimethyldihydropyrene (DHP) derivative have been investigated for the first time in single-molecule junctions using the mechanically controllable break junction technique. We demonstrate that the reversible structure changes induced by isomerization of a single bispyridine-substituted DHP molecule are correlated with a large drop of the conductance value. We found a very high ON/OFF ratio (>104) and an excellent reversibility of conductance switching. |
| Formato |
application/pdf |
| Identificador |
http://boris.unibe.ch/39860/1/ja401484j.pdf Roldan, Diego; Kaliginedi, Veerabhadrarao; Cobo, Saioa; Kolivoska, Viliam; Bucher, Christophe; Hong, Wenjing; Royal, Guy; Wandlowski, Thomas (2013). Charge Transport in Photoswitchable Dimethyldihydropyrene-Type Single-Molecule Junctions. Journal of the American Chemical Society, 135(16), pp. 5974-5977. American Chemical Society 10.1021/ja401484j <http://dx.doi.org/10.1021/ja401484j> doi:10.7892/boris.39860 info:doi:10.1021/ja401484j urn:issn:0002-7863 |
| Idioma(s) |
eng |
| Publicador |
American Chemical Society |
| Relação |
http://boris.unibe.ch/39860/ |
| Direitos |
info:eu-repo/semantics/restrictedAccess |
| Fonte |
Roldan, Diego; Kaliginedi, Veerabhadrarao; Cobo, Saioa; Kolivoska, Viliam; Bucher, Christophe; Hong, Wenjing; Royal, Guy; Wandlowski, Thomas (2013). Charge Transport in Photoswitchable Dimethyldihydropyrene-Type Single-Molecule Junctions. Journal of the American Chemical Society, 135(16), pp. 5974-5977. American Chemical Society 10.1021/ja401484j <http://dx.doi.org/10.1021/ja401484j> |
| Palavras-Chave | #570 Life sciences; biology #540 Chemistry |
| Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion PeerReviewed |
