Odorless Preparation Of Thioglycosides And Thio Michael Adducts Of Carbohydrate Derivatives
| Data(s) |
28/12/2007
28/12/2007
2007
|
|---|---|
| Resumo |
A generalized, odorless, one-pot methodology has been developed for the preparation of 1,2-trans-thioglycosides and thio-Michael addition products of carbohydrate derivatives through triphenyl phosphine mediated cleavage of disulfides and reaction of the thiolate formed in situ with glycosyl bromides and glycosyl conjugated alkenes. |
| Formato |
132962 bytes application/pdf |
| Identificador |
J. Carbohydrate Chemistry (2007), 26, 213-221 |
| Idioma(s) |
en |
| Relação |
C.D.R.I. communication no. 6909. |
| Palavras-Chave | #Carbohydrate #cleavage reactions #thioglycosides #triphenyl phosphine. #conjugate addition |
| Tipo |
Article |