Odorless Preparation Of Thioglycosides And Thio Michael Adducts Of Carbohydrate Derivatives
Data(s) |
28/12/2007
28/12/2007
2007
|
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Resumo |
A generalized, odorless, one-pot methodology has been developed for the preparation of 1,2-trans-thioglycosides and thio-Michael addition products of carbohydrate derivatives through triphenyl phosphine mediated cleavage of disulfides and reaction of the thiolate formed in situ with glycosyl bromides and glycosyl conjugated alkenes. |
Formato |
132962 bytes application/pdf |
Identificador |
J. Carbohydrate Chemistry (2007), 26, 213-221 |
Idioma(s) |
en |
Relação |
C.D.R.I. communication no. 6909. |
Palavras-Chave | #Carbohydrate #cleavage reactions #thioglycosides #triphenyl phosphine. #conjugate addition |
Tipo |
Article |