Fe valence fluctuations and magnetoelastic coupling in Pb-based multiferroics perovskites


Autoria(s): Fraygola, Barbara; Mesquita, Alexandre; Coelho, Adelino A.; Garcia, Ducinei; Mastelaro, Valmor Roberto; Eiras, Jose A.
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

09/06/2014

09/06/2014

01/02/2013

Resumo

Lead-based multiferroics perovskites with nominal compositions Pb(Fe1/2Nb1/2)O3 and Pb(Fe2/3W1/3)O3 were synthesized following a two-stage method. Magnetic proprieties were investigated and correlated to anelastic proprieties, measured by the conventional pulse-echo method. The discussions are focused in the region around 250 K, where magnetoelectroelastic instabilities have been observed. X-ray absorption nearedge structure (XANES) study further indicates that the edge position varies with temperature revealing a fluctuation on the valence of iron ions with the temperature, which can be related to a variation in anelastic and magnetic proprieties.

FAPESP (08/04025-0, 10/11187-6)

CNPq

Identificador

Physica Status Solidi A, Weinheim : Wiley-VCH Verlag, v. 210, n. 2, p. 386-390, Feb. 2013

1862-6300

http://www.producao.usp.br/handle/BDPI/45331

10.1002/pssa.201228376

Idioma(s)

eng

Publicador

Wiley-VCH Verlag

Weinheim

Relação

Physica Status Solidi A

Direitos

restrictedAccess

Copyright WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Palavras-Chave #Anelastic #Multiferroics #PFN #PFW #XANES #MATERIAIS CERÂMICOS #PROPRIEDADES DOS MATERIAIS #FERROMAGNETISMO
Tipo

article

original article

publishedVersion