On the optical properties of copper nanocubes as a function of the edge length as modeled by the discrete dipole approximation


Autoria(s): Alves, Tiago V.; Hermoso, Willian; Ornellas, Fernando Rei; Camargo, Pedro Henrique Cury de
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

07/11/2013

07/11/2013

2012

Resumo

This Letter reports an investigation on the optical properties of copper nanocubes as a function of size as modeled by the discrete dipole approximation. In the far-field, our results showed that the extinction resonances shifted from 595 to 670 nm as the size increased from 20 to 100 nm. Also, the highest optical efficiencies for absorption and scattering were obtained for nanocubes that were 60 and 100 nm in size, respectively. In the near-field, the electric-field amplitudes were investigated considering 514, 633 and 785 nm as the excitation wavelengths. The E-fields increased with size, being the highest at 633 nm. (c) 2012 Elsevier B.V. All rights reserved.

FAPESP

FAPESP [2011/06847-0]

CNPq

CNPq

University of Sao Paulo

University of Sao Paulo [11.1.25042.1.0]

Identificador

CHEMICAL PHYSICS LETTERS, AMSTERDAM, v. 544, n. 6, p. 64-69, AUG 20, 2012

0009-2614

http://www.producao.usp.br/handle/BDPI/42870

10.1016/j.cplett.2012.07.001

http://dx.doi.org/10.1016/j.cplett.2012.07.001

Idioma(s)

eng

Publicador

ELSEVIER SCIENCE BV

AMSTERDAM

Relação

Chemical Physics Letters

Direitos

closedAccess

Copyright ELSEVIER SCIENCE BV

Palavras-Chave #ENHANCED RAMAN-SCATTERING #SHAPE-CONTROLLED SYNTHESIS #SURFACE-PLASMON RESONANCE #METAL NANOPARTICLES #BIOMEDICAL APPLICATIONS #SILVER NANOSTRUCTURES #AQUEOUS-SOLUTION #NANOCRYSTALS #LATTICE #DIMERS #CHEMISTRY, PHYSICAL #PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
Tipo

article

original article

publishedVersion