Detailed H-1 and C-13 NMR structural assignment and relative stereochemistry determination for three new and one known semi-synthetic sesquiterpene lactones
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
07/11/2013
07/11/2013
2012
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| Resumo |
In this work is described a complete H-1 and C-13 NMR analysis for a group of four sesquiterpene lactones, three previously unknown. The unequivocal assignments were achieved by H-1 NMR, C-13{H-1} NMR, gCOSY. gHMQC, gHMBC and NOESY experiments and no ambiguities were left behind. All hydrogen coupling constants were measured, clarifying all hydrogen signals multiplicities. (C) 2011 Elsevier B.V. All rights reserved. FAPESP FAPESP CAPES CAPES CNPq CNPq |
| Identificador |
JOURNAL OF MOLECULAR STRUCTURE, AMSTERDAM, v. 1008, n. 4, supl. 6, Part 1, pp. 24-28, 45658, 2012 0022-2860 http://www.producao.usp.br/handle/BDPI/42783 10.1016/j.molstruc.2011.11.012 |
| Idioma(s) |
eng |
| Publicador |
ELSEVIER SCIENCE BV AMSTERDAM |
| Relação |
JOURNAL OF MOLECULAR STRUCTURE |
| Direitos |
closedAccess Copyright ELSEVIER SCIENCE BV |
| Palavras-Chave | #H-1 NMR #C-13 NMR #2D NMR #SESQUITERPENE LACTONES #FURANOHELIANGOLIDES #CONJUGATE REDUCTION #STRYKERS REAGENT #FURANOHELIANGOLIDE #GUAIANOLIDE #OXYGEN #CHEMISTRY, PHYSICAL |
| Tipo |
article original article publishedVersion |
