Crystal structure and spectroscopic properties of polymeric adducts of the tetra-mu-haloaspirinate-dicopper(II)
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
06/11/2013
06/11/2013
2012
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| Resumo |
Eight new copper(II) complexes with halo-aspirinate anions have been synthesized: [Cu-2(Fasp)(4)(MeCN)(2)] center dot 2MeCN (1), [Cu-2(Clasp)(4)(MeCN)(2)]center dot 2MeCN (2), [Cu-2(Brasp)(4) (MeCn)(2)] center dot 2MeCn (3), {[Cu-2(Fasp)(4)(Pyrz)] center dot 2MeCN}(n) (4) {[Cu-2(Clasp)(4)(Pyrz)] center dot 2MeCN}(n) (5), [Cu-2(Brasp)(4)(Pyrz)](n) (6), [Cu-2(Clasp)(4)(4,4'-Bipy)](n) (7), and [Cu-2(Brasp)(4)(4,4'-Bipy)](n) (8) (Fasp: fluor-aspirinate; Clasp: chloro-aspirinate; Brasp: bromo-aspirinate; MeCN: acetonitrile; Pyrz: pyrazine; 4,4'-Bipy: 4,4'-bipyridine). The crystal structure of two 2 and 4 have been determined by X-ray diffraction methods. All compounds have been studied employing elemental analysis, IR, and UV-Visible spectroscopic techniques. The results have been compared with previous data reported for complexes with similar structures. SGCyT of UNS SGCyT of UNS [M24/081] CONICET of Argentina CONICET of Argentina FAPESP of Brazil FAPESP of Brazil CONICET CONICET |
| Identificador |
JOURNAL OF COORDINATION CHEMISTRY, ABINGDON, v. 65, n. 13, supl. 4, Part 1-2, pp. 2341-2352, DEC, 2012 0095-8972 http://www.producao.usp.br/handle/BDPI/42017 10.1080/00958972.2012.691477 |
| Idioma(s) |
eng |
| Publicador |
TAYLOR & FRANCIS LTD ABINGDON |
| Relação |
JOURNAL OF COORDINATION CHEMISTRY |
| Direitos |
restrictedAccess Copyright TAYLOR & FRANCIS LTD |
| Palavras-Chave | #COPPER(II) COMPLEXES #HALOASPIRINATE ANIONS #CRYSTAL STRUCTURES #COPPER(II) COMPLEXES #MAGNETIC-PROPERTIES #ANTIINFLAMMATORY DRUGS #MIMETIC ACTIVITY #MONONUCLEAR #BINUCLEAR #LIGANDS #ACID #BIS(DIMETHYL #DERIVATIVES #CHEMISTRY, INORGANIC & NUCLEAR |
| Tipo |
article original article publishedVersion |
