Novel cross-coupling reactions between organotellurides and Grignard reagents employing a MnCl2/CuI catalytic system
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
06/11/2013
06/11/2013
2012
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| Resumo |
We present a general protocol for the cross-coupling reaction of Grignard reagents and organic tellurides. Aryl Grignard reagents react stereospecifically with vinyl tellurides in the presence of a catalytic amount of manganese (II) chloride and copper (I) iodide to produce good yields of the corresponding cross-coupling products. (C) 2012 Published by Elsevier Ltd. FAPESP FAPESP CNPq CNPq CAPES CAPES |
| Identificador |
TETRAHEDRON LETTERS, OXFORD, v. 53, n. 28, pp. 3556-3559, 40725, 2012 0040-4039 http://www.producao.usp.br/handle/BDPI/41958 10.1016/j.tetlet.2012.04.134 |
| Idioma(s) |
eng |
| Publicador |
PERGAMON-ELSEVIER SCIENCE LTD OXFORD |
| Relação |
TETRAHEDRON LETTERS |
| Direitos |
closedAccess Copyright PERGAMON-ELSEVIER SCIENCE LTD |
| Palavras-Chave | #MANGANESE (II) CHLORIDE #CROSS-COUPLING REACTION #ORGANOMETALLIC REAGENTS #CATALYSIS #ORGANIC TELLURIDES #VINYLIC TELLURIDES #ORGANIC-SYNTHESIS #ARYL-GRIGNARD #COMPLEXES #HALIDES #CHEMISTRY, ORGANIC |
| Tipo |
article original article publishedVersion |
