Materials prepared from biopolyethylene and curaua fibers: Composites from biomass


Autoria(s): Castro, D. O.; Ruvolo-Filho, A.; Frollini, E.
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

07/11/2013

07/11/2013

2012

Resumo

Composites of high-density biopolyethylene (HDBPE) obtained from ethylene derived from sugarcane ethanol and curaua fibers were formed by first mixing in an internal mixer followed by thermopressing. Additionally, hydroxyl-terminated polybutadiene (LHPB), which is usually used as an impact modifier, was mainly used in this study as a compatibilizer agent. The fibers, HDBPE and LHPB were also compounded using an inter-meshing twin-screw extruder and, subsequently, injection molded. The presence of the curaua fibers enhanced some of the properties of the HDBPE, such as its flexural strength and storage modulus. SEM images showed that the addition of LHPB improved the adhesion of the fiber/matrix at the interface, which increased the impact strength of the composite. The higher shear experienced during processing probably led to a more homogeneous distribution of fibers, making the composite that was prepared through extruder/injection molding more resistant to impact than the composite processed by the internal mixer/thermopressing. (c) 2012 Elsevier Ltd. All rights reserved.

Capes (Coordination for the Improvement of Higher Education Personnel, Brazil)

FAPESP (The State of Sao Paulo Research Foundation, Brazil)

FAPESP (The State of Sao Paulo Research Foundation, Brazil)

CNPq (National Research Council, Brazil)

Identificador

POLYMER TESTING, OXFORD, v. 31, n. 7, pp. 880-888, OCT, 2012

0142-9418

http://www.producao.usp.br/handle/BDPI/43141

10.1016/j.polymertesting.2012.05.011

http://dx.doi.org/10.1016/j.polymertesting.2012.05.011

Idioma(s)

eng

Publicador

ELSEVIER SCI LTD

OXFORD

Relação

POLYMER TESTING

Direitos

closedAccess

Copyright ELSEVIER SCI LTD

Palavras-Chave #HIGH DENSITY BIOPOLYETHYLENE #LIGNOCELLULOSIC FIBERS #CURAUA #SUGAR-CANE BAGASSE #REINFORCED POLYPROPYLENE COMPOSITES #MECHANICAL-PROPERTIES #POLYETHYLENE COMPOSITES #PHENOLIC MATRICES #FURFURYL ALCOHOL #THERMAL-PROPERTIES #FRACTURE-BEHAVIOR #BLENDS #CELLULOSE #MATERIALS SCIENCE, CHARACTERIZATION & TESTING #POLYMER SCIENCE
Tipo

article

original article

publishedVersion