Magnetic nanohydrometallurgy: A promising nanotechnological approach for metal production and recovery using functionalized superparamagnetic nanoparticles


Autoria(s): Condomitti, Ulisses; Zuin, Andre; Silveira, Alceu T.; Araki, Koiti; Toma, Henrique E.
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

25/09/2013

25/09/2013

2012

Resumo

We report on a new, promising nanotechnological approach for hydrometallurgy based on recyclable, chemically functionalized superparamagnetic nanoparticles. In this process, the metal ions (e.g. Cu2+) are captured by the nanoparticles and confined at the electrode surface by means of an external magnet. Due to the pre-concentration effect the electrodeposition process is greatly improved, yielding the pure metal in a much shorter time in comparison with the conventional electrodeposition process. After the electrolysis, the magnetic nanoparticles are ready to return to the process. The proposed strategy can advantageously be incorporated in hydrometallurgy, reducing the number of steps associated with complexation, organic solvent extraction, metal release and diffusional electroprocessing, leading to a more sustainable technology. (C) 2012 Elsevier B.V. All rights reserved.

FAPESP

FAPESP

CNPq

CNPq

PETROBRAS

PETROBRAS

Identificador

HYDROMETALLURGY, AMSTERDAM, v. 125, n. 7, pp. 148-151, AUG, 2012

0304-386X

http://www.producao.usp.br/handle/BDPI/33723

10.1016/j.hydromet.2012.06.005

http://dx.doi.org/10.1016/j.hydromet.2012.06.005

Idioma(s)

eng

Publicador

ELSEVIER SCIENCE BV

AMSTERDAM

Relação

HYDROMETALLURGY

Direitos

restrictedAccess

Copyright ELSEVIER SCIENCE BV

Palavras-Chave #MAGNETIC NANOHYDROMETALLURGY #SUPERPARAMAGNETIC NANOPARTICLES #COPPER ELECTRODEPOSITION #IRON-OXIDE NANOPARTICLES #SOLVENT-EXTRACTION #CIRCUIT BOARDS #COPPER #ELECTROLYTE #METALLURGY & METALLURGICAL ENGINEERING
Tipo

article

original article

publishedVersion